Preparation, structural studies and chemical properties of new hypervalent iodine compounds

Abstract

This work describes two independent research projects. The first one is focused on preparation of a new class of heterocyclic hypervalent iodine (III) compounds, the benziodoxaboroles, and a series of heterocyclic compounds containing trivalent iodine, oxygen, and boron in a five-membered ring were prepared and structurally investigated by X-ray crystallography. Second project is related to the development of new environmentally friendly hypervalent iodine (V) reagent and methods for oxidative iodination of arenes.