Redox non-innocence and formation of nitrogen-nitrogen bonds in organometallic reactions
2020-01
Loading...
View/Download File
Persistent link to this item
Statistics
View StatisticsJournal Title
Journal ISSN
Volume Title
Title
Redox non-innocence and formation of nitrogen-nitrogen bonds in organometallic reactions
Authors
Published Date
2020-01
Publisher
Type
Thesis or Dissertation
Abstract
The utilization of redox non-innocent ligands and substrates can grant access to new modes of reactivity in organometallic chemistry, allowing for the development of new sustainable methods with earth-abundant catalysts. Through the use of valence tautomerism in nitrogenous ligands and substrates (azides, azobenzene, isodiazenes, etc.), new organometallic reactions have been developed—the atom economical synthesis of important organic molecules such as pyrroles, pyrazoles and imines through titanium redox catalysis and an exploration of the valence tautomerism of an iridium(III)-hydrazido(2-) capable of oxidative addition.
Description
University of Minnesota Ph.D. dissertation. January 2020. Major: Chemistry. Advisor: Ian Tonks. 1 computer file (PDF); 3 xxv, 276 pages.
Related to
Replaces
License
Collections
Series/Report Number
Funding information
Isbn identifier
Doi identifier
Previously Published Citation
Suggested citation
Pearce, Adam. (2020). Redox non-innocence and formation of nitrogen-nitrogen bonds in organometallic reactions. Retrieved from the University Digital Conservancy, https://hdl.handle.net/11299/213094.
Content distributed via the University Digital Conservancy may be subject to additional license and use restrictions applied by the depositor. By using these files, users agree to the Terms of Use. Materials in the UDC may contain content that is disturbing and/or harmful. For more information, please see our statement on harmful content in digital repositories.