Extraction of Copper from Chalcopyrite Concentrates without Sulfuric Acid Generation via Chlorination - I. Gaseous Chlorination of Sulfide Concentrates

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Extraction of Copper from Chalcopyrite Concentrates without Sulfuric Acid Generation via Chlorination - I. Gaseous Chlorination of Sulfide Concentrates

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2000

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University of Minnesota Duluth

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Technical Report

Abstract

A gaseous chlorination process for hydrometallurgical treatment of a chalcopyrite concentrate was investigated. The overall process is visualized to consist of low temperature chlorination-selective oxidation, followed ยท by aqueous chloride leaching and SX-EW for producing electrolytic copper, elemental sulfur and ferric oxide. In this article, the chlorination phase of the process is described. Initially, the chlorination behavior of chalcopyrite-concentrate micro-pellets was investigated using a small batch-type fluidized bed reactor. The optimum conditions thereby established were used in continuous chlorination tests. The chlorinated products thus prepared were used in the selective oxidation phase of the investigation.

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Iwasaki, Iwao; Tamagawa, T.; Tabaian, S. H; Fu, N. X; Kobayashi, M. (2000). Extraction of Copper from Chalcopyrite Concentrates without Sulfuric Acid Generation via Chlorination - I. Gaseous Chlorination of Sulfide Concentrates. Retrieved from the University Digital Conservancy, https://hdl.handle.net/11299/187124.

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