Geology and Mineralization of a Cyclic Layered Series, Water Hen Intrusion, St. Louis County, Minnesota

Abstract

The Water Hen intrusion is an oxide-bearing (ilmenite + magnetite) ultramafic intrusion (OUI) that is emplaced along a pre-basement fault into the troctolitic series rocks of the Duluth Complex. The intrusion consists of medium-grained dunite and peridotite and local pegmatitic pyroxenite approximately 1,600 ft. x 500 ft. x 700 ft. in size. Oxide (>90% ilmenite) composes from 5-50% of the various lithologies. Sulfides are minor, about 2-5%, and are predominantly pyrrhotite with minor cubanite, chalcopyrite and pentlandite. Concentrations of 5-80% graphite also occur within the intrusion. Surrounding the Water Hen intrusion is a zone of mixed lithologies (Mixed Zone) consisting of the host rock troctolites, apophyses of OUI and local inclusions of footwall rocks. The Mixed Zone (M) is dominated by >60% troctolitic rocks with OUI composing the remainder. The OUI apophyses vary from 1-50 ft. thick and have sharp contacts with the country rock. The troctolitic host rocks for the Water Hen intrusion consist of medium- to coarsegrained troctolite to anorthositic troctolite (TA unit) and a troctolitic cyclically layered series (TL unit). The cyclically layered series is similar to troctolitic layered rocks at Bardon Peak. The individual cyclic layers are 6 in. to 10 ft. in thickness and the entire unit is over 300 ft. thick. The An content decreases from An80 at the bottom of the unit to An60 near the top of the unit. The individual cyclic layers are composed of ilmenite-dunite at the base and grade upward to anorthositic troctolite. The bottom contacts are sharp and each successive layer within the individual unit is identified by the occurrence of biotite or clinopyroxene. In the bottom olivine-rich layer, the oxides (<5%) are ilmenite >> magnetite. The sulfides in this same layer (3-5%) are coarse-grained with cubanite > chalcopyrite > pentlandite >> pyrrhotite. In the more feldspathic layers, the sulfides (1-3%) are fine-grained with chalcopyrite >> pentlandite = cubanite + pyrrhotite. The oxides (1- 5%) are also fine-grained with ilmenite >> magnetite. The footwall rocks in the Water Hen area consist of very fine-grained metamorphosed Virginia Formation and fine-grained hornfelsed basalt and/or troctolite. There are >100 ft. of basalt or chilled margin rocks within the footwall. This mafic hornfels commonly occurs between the Virginia Formation and the TA unit. Orthopyroxenite dikes and dikelets also occur in the mafic hornfels. These dikes contain anomalous PGEs and secondary sulfide mineralization. The copper-nickel sulfides are primary igneous sulfides associated with the troctolitic rocks. Violarite, pyrite and secondary magnetite in cross-cutting veinlets and other secondary sulfides indicate that the primary sulfides were altered and remobilized by a later event. Cu:Ni ratios have a bimodal distribution that is not followed by the PGEs. However, Cu, Ni, Ag, Au, Pt, Pd are all highly correlated with each other. This high interelement correlation suggests that the late-stage (secondary) remobilization locally redistributed and reconcentrated these elements.