Controlling Optical Transport in Luminescent Solar Concentrators
2019-05
Loading...
View/Download File
Persistent link to this item
Statistics
View StatisticsJournal Title
Journal ISSN
Volume Title
Title
Controlling Optical Transport in Luminescent Solar Concentrators
Authors
Published Date
2019-05
Publisher
Type
Thesis or Dissertation
Abstract
Luminescent solar concentrators (LSCs) improve solar cell performance by transforming the spectrally broad and partially diffuse solar spectrum into a spectrally narrow and focused light source, which is then concentrated onto a small-area solar cell. However, LSCs do not currently reach their full concentrating potential due to losses in the system that prevent luminescent light from reaching the edge of the concentrator, including light scattering and coupling to the escape cone. In order to reduce escape cone losses within LSCs, nanophotonic structures were designed for concentrators with CdSe/CdS core/shell nanocrystals. Using a combination of Monte Carlo ray-tracing simulations and FDTD simulations we show that concentration factor improvements of 3.7 times the standard concentrator are achievable when spectrally-selective mirrors are placed on top of the LSC. Further enhancements to the optical efficiency are possible when the emitted light is controlled either by a phase gradient metasurface or the directional emission of a nanophotonic stack of alternating high and low refractive index layers. Finally, we show that directional emission is also expected for a nanoscale thin film LSC on glass, which can also be fabricated by embedding CdSe/CdS in poly (cyclohexylethylene), a new polymer for LSC applications. To reduce scattering losses for LSCs, new surface ligands have been proposed for Si nanocrystals that improve dispersion in polymer matrices. In this collaboration, I characterized Si/poly (methyl methacrylate) composites and showed that the scattering losses are reduced by six fold using these new surface ligands when compared to previous methods. The design criteria established in this work demonstrate that nanophotonic structures can control the optical transport in LSCs, and that low scattering quantum dot/polymer composites are essential to realize high performance. The ability to control the light guiding properties in LSCs will be crucial for high quality LSCs and future implementation into building integrated photovoltaic technologies.
Keywords
Description
University of Minnesota Ph.D. dissertation. May 2019. Major: Material Science and Engineering. Advisor: Vivian Ferry. 1 computer file (PDF); xiv 166 pages.
Related to
Replaces
License
Collections
Series/Report Number
Funding information
Isbn identifier
Doi identifier
Previously Published Citation
Other identifiers
Suggested citation
Connell, Ryan. (2019). Controlling Optical Transport in Luminescent Solar Concentrators. Retrieved from the University Digital Conservancy, https://hdl.handle.net/11299/206306.
Content distributed via the University Digital Conservancy may be subject to additional license and use restrictions applied by the depositor. By using these files, users agree to the Terms of Use. Materials in the UDC may contain content that is disturbing and/or harmful. For more information, please see our statement on harmful content in digital repositories.