Methods for Directed C–O Bond Functionalization of Esters and Acyl Equivalents

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Methods for Directed C–O Bond Functionalization of Esters and Acyl Equivalents

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Underwood, Steven

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2022-12

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Abstract

A summary of work developing and studying the mechanisms of new transition metal-catalyzed acyl transfer reactions using substrates at the ester oxidation state. New methods discussed include steric-controlled arene acylation via sequential C–O/C–H bond activation and a Suzuki-Miyaura cross coupling using N-pyridylimidates as acyl equivalents.

Keywords

Bond activation

Organic synthesis

Transition metal catalysis

Description

University of Minnesota Ph.D. dissertation. December 2022. Major: Chemistry. Advisor: Christopher Douglas. 1 computer file (PDF); xi, 178 pages.

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Underwood, Steven. (2022). Methods for Directed C–O Bond Functionalization of Esters and Acyl Equivalents. Retrieved from the University Digital Conservancy, https://hdl.handle.net/11299/253736.

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