Dye Tracing Through Thick Unsaturated Zones

Abstract

Using the fluorescent dye Rhodamine WT, a field fluorometer, and direct samples of water collected from springs, wells, cave drips, and pools we have conducted two successful dye traces through thick unsaturated zones in karst regions. The first dye trace was of a proposed expansion site for a landfill in Winona County, southeastern Minnesota. The site sits on top of a narrow ridge about 150 meters above the adjacent valleys. The second trace was at Jewel Cave National Monument in the southern Black Hills of South Dakota. This trace was initiated to evaluate the impact of tourist facilities on the underlying cave. A visitor center was constructed on the surface, 50 to 100 meters directly above the cave. In both traces, small, irregular pulses of dye began to appear (in springs and wells at the Winona Landfill site and in cave drips and pools at Jewel Cave) within days of the dye injection, and the pulses continued to emerge for months. The pulses were typically a day or less in duration and a very small (10s to 100s of parts per trillion, 10- 12 g/g). The pulses are more frequent after major precipitation/runoff events but appear to be moving through both unsaturated zones in a very irregular, stochastic fashion. The very low levels of dye detected in many of the pulses required so.me type of confirmation analysis. We have successfully used the large negative temperature coefficient of Rhodamine WT's fluorescence to discriminate between low levels of Rhodamine WT and fluorescence due to background materials.