Browsing by Author "Kumar, Prashant"

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    Satisfaction with travel, ideal commuting, and accessibility to employment
    (Journal of Transport and Land Use, 2021) Pritchard, John P.; Geurs, Karst; Tomasiello, Diego B.; Slovic, Anne Dorothee; Nardocci, Adelaide; Kumar, Prashant; Giannotti, Mariana; Hagen-Zanker, Alex
    This paper explores relationships between commuting times, job accessibility, and commuting satisfaction based on a large-scale survey applied in the Greater London Area (GLA), the municipality of São Paulo (MSP) and the Dutch Randstad (NLR). Potential accessibility to jobs is estimated under 3 different scenarios: reported actual commuting times (ACT), ideal commuting times (ICT), and maximum willingness to commute (MCT). In addition, binary logistic regression models, estimated using generalized linear modeling (GLM), are performed to assess the impact of these temporal preferences on the likelihood of being satisfied with commuting. As expected, ideal and maximum commuting preferences strongly impact the volume and spatial distribution of the measured accessibility to jobs. In the selected case studies, estimated ICT-based job accessibility significantly decreases total measured accessibility (60 to 100 percent), with those living in the lowest accessibility zones impacted most. Furthermore, although specific results varied between regions, the overall findings show an association between ACT and satisfaction. Likewise, commuting mode is found to be a strong predictor of travel satisfaction. Those actively traveling in all three metropolitan regions tend to be more satisfied with their commutes. Potential job accessibility is found to be only weakly associated with travel satisfaction.
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    Structural Investigation of Electron-Beam Sensitive Zeolites and Metal-Organic-Frameworks Using Analytical Transmission Electron Microscopy
    (2018-08) Kumar, Prashant
    An interesting class of materials that has become ubiquitous in our daily lives is the family of zeolites, which are porous scaffolds made of silicon, oxygen and aluminum atoms. Zeolites act like a coffee filter paper with pores of molecular dimensions that can be tailored to separate molecules of different diameters by adjusting the sizes of the pore openings from 2 Å (1 Å = 0.0000000001 m) to 10 Å. For example, over 90% of commercially available detergents contain zeolites, which act as water softeners by selectively removing calcium and magnesium ions from water, while any product that can be traced back to a petrochemical refinery (like fuels, chemicals and pharmaceutics) contains molecules that have passed through selective zeolite pores numerous times. To date, 231 unique zeolite frameworks have been synthesized while computer simulations predict over 330,000 new structures. TEM imaging and electron diffraction has contributed in the crystal structure determination of many of the known 231 synthesized zeolite frameworks. However, the recent development of few-atom-thick zeolites (2-dimensional zeolite nanosheets) and new classes of porous materials based on metal-organic-frameworks (MOFs) pose new demands and create new opportunities for electron microscopy. The objective of this dissertation work is to determine the atomic arrangement in zeolite nanosheets and metal organic frameworks using transmission electron microscopy to develop a fundamental relationship between their crystal structure and performance as catalysts and membranes. Using electron diffraction, imaging, spectroscopy and digital image processing, TEM data acquisition and analysis routines have been developed to mitigate electron beam sensitivity of these materials. Implementation of the developed routines enabled crystal structure, growth and defect analysis down to the atomic scale, leading to novel findings and implications discussed in detail here.