Browsing by Author "Davis, Frederick Arthur"

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    Determination of small melt fraction peridotite partial melts using re foil melt traps
    (2011-03) Davis, Frederick Arthur
    The global record of trace element and isotopic compositions of ocean island basalts (OIB) suggest that they are derived from several distinct reservoirs in the mantle. Major and minor element compositions of OIB also span a relatively large range of compositions when compared with the more nearly uniform basaltic compositions erupted at mid-ocean ridges. This may be due to distinct melting lithologies or conditions of melting beneath different oceanic islands. The upper mantle is widely believed to be composed primarily of peridotite, which likely contributes to the formation of OIB. Melting at most OIB localities is confined to depths beneath the rigid oceanic lithosphere (~100 km) at pressures ~3 GPa where garnet is the stable aluminous phase, and the high incompatible element concentrations in these basalts suggest that melting is limited to low melt fractions. Thus, identifying the composition of low melt fraction partial melts of garnet peridotite at 3 GPa is key to understanding the genesis of OIB. Low melt fraction partial melts of garnet peridotite were produced experimentally at 3 GPa in a piston cylinder apparatus using a new Re-foil melt trap. Melt traps allow partial melts to be segregated from crystalline residues, preventing changes in the compositions of small melt pools that can result from crystallization onto nearby mineral grains while the experiment is quenching. Re-foil melt traps are similar to diamond aggregate and vitreous carbon sphere traps, but rely upon the wetting properties of Re as well as pressure gradients to attract the melt phase. Re traps are easier to polish than diamond traps and, unlike vitreous carbon spheres, are capable of withstanding high temperatures required for peridotite partial melting at 3 GPa Partial melting experiments were performed in Pt/C capsules containing natural peridotite powder, KLB-1, or an oxide mixture approaching the composition of KLB-1. Experiments were performed from 1470-1530 °C and produced melt fractions between 0.059 and 0.235. In contrast with previous peridotite melting studies at 3 GPa, melts in the lowest melt fraction experiments coexisted with garnet. Resulting melt compositions are similar to those found by other peridotite partial melting studies for many components, including: TiO2, Cr2O3, MnO, MgO, and Na2O; however, there are relatively large differences in FeO* and CaO from the melt compositions of Walter (1998). FeO* in Re trap experiments varies from 6.6-7.9%, considerably lower than the Walter (1998) melts which are never lower than 8.8% FeO* at 3 GPa, and CaO varies from 11.4-14.3%, significantly higher than melts in Walter (1998) that vary from 7.7- 10.9%. The Re trap method successfully produces large melt pools that can be analyzed by electron microprobe at melt fractions as low as 0.05, although this may be about the lower limit of its effectiveness. The disagreements with previous experiments in CaO and FeO* contents are likely the result of the heterogeneous character of the melt pools and cast doubt on whether the measured compositions of melts produced in these experiments are true low-degree peridotite melt compositions.
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    The role of partial melts of peridotite in the formation of oceanic island basalts.
    (2012-08) Davis, Frederick Arthur
    Despite the classic hypothesis that primary basalts are generated by partial melting of peridotite, several compositional characteristics of oceanic island basalts (OIB) are not easily reconciled with such an origin. Many OIB have higher FeO and lower Al2O3 concentrations than do experimentally-derived partial melts of peridotite; however experiments have not been performed at both the high pressures (3 GPa) and low melt fractions relevant to OIB formation. Trace element concentrations and ratios of many first-row transition elements (FRTE) in OIB and associated phenocrysts may also suggest that non-peridotitic melting lithologies play a role in OIB petrogenesis. This thesis presents the results of high-pressure experiments designed to test the hypothesis that oceanic island basalts (OIB) can be derived solely by partial melting of a peridotite source. Experiments were performed in a piston cylinder apparatus at 3 GPa and temperatures near the solidus of peridotite (1430-1470 °C). Experiments to determine the major-element composition of the incipient melt of garnet lherzolite employed a recently developed technique, modified iterative sandwich experiments (MISE), which simulates near-solidus partial melting while allowing for the preservation of large melt pools to facilitate chemical analysis. The resulting melts are similar to alkalic OIB in many respects, but are still higher in Al2O3 (12.7±0.2 wt.%) and lower in FeO* (9.7±0.1 wt.%) than most OIB. Trace element partitioning experiments were performed to determine mineral/melt partition coefficients for several FRTE (Sc, Ti, V, Cr, Mn, Fe, Co, Zn) and Ga and Ge during partial melting of peridotite. Experiments were cooled slowly from ≥50 °C above the intended dwell temperature to facilitate growth of large crystals for trace element analysis by LA-ICP-MS. Measured partition coefficients form the basis of a partial melting model that predicts FRTE concentrations and ratios in partial melts of peridotite at 3 GPa. Partial melts of peridotite have Fe/Mn < 62, Zn/Fe < 13*10-4, and Co/Fe > 7*10-4. Many OIB have higher Fe/Mn and lower Co/Fe than can be obtained by partial melting of peridotite, at least under relatively reducing conditions. Experiments were performed using the starting compositions from the MISE experiments but with added K2O in the melt to determine the effects of K2O on the composition of near-solidus melts of peridotite at 3 GPa. In resulting melts SiO2 increases and CaO decreases by ~0.5 wt.% for each 1 wt.% increase in the K2O content of the melt. Al2O3 increases and Cr2O3 and Na2O decrease with increasing K2O content of the melt. Increased K2O content moves the compositions of near-solidus melts of peridotite toward the low-CaO, high-SiO2 EM-type OIB, but the effect is not strong enough to match these compositions at comparable K2O concentrations. Spinel lherzolite KLB-1, which is used as a starting material in many high pressure experiments, was analyzed for major and minor elements. To perform the bulk analysis, powdered KLB-1 was glassed by laser melting of aerodynamically levitated spheroids. The glass beads and minerals separates from the powdered sample were analyzed by electron microprobe analysis. This measurement resolves conflicting FeO, CaO, and TiO2 values from two older measurements, and allows for an improved estimate of the modal proportion of mineral phases determined by mass balance.