Bis-phenoxides as Ligands for Ti-mediated Hydroamination and Pyrrole Formation Catalysis
2023-08
Loading...
View/Download File
Persistent link to this item
Statistics
View StatisticsJournal Title
Journal ISSN
Volume Title
Title
Bis-phenoxides as Ligands for Ti-mediated Hydroamination and Pyrrole Formation Catalysis
Authors
Published Date
2023-08
Publisher
Type
Thesis or Dissertation
Abstract
This thesis covers the development of a new aryl-linked bis-phenoxide ligand, its use in synthesis of Ti complexes, and the catalytic utility of those complexes for hydroamination and pyrrole synthesis. Chapter 1 outlines the literature background for Ti-catalyzed hydroamination and pyrrole synthesis. Chapter 2 describes the synthesis of the bis-phenoxide ligand, its use in Ti-complexes, and the ability of those complexes to catalyze hydroamination reactions. Chapter 3 details a transfer hydrogenation/pyrrole synthesis reactions using the same Ti-complexes. Chapter 4 discusses efforts to isolate a low-valent species using the aryl-linked bis-phenoxide ligand and improve on the ligand via extension of the center aryl linker.
Keywords
Description
University of Minnesota Ph.D. dissertation. August 2023. Major: Chemistry. Advisor: Ian Tonks. 1 computer file (PDF); xv, 150 pages.
Related to
Replaces
License
Collections
Series/Report Number
Funding information
Isbn identifier
Doi identifier
Previously Published Citation
Suggested citation
Butler, Steven. (2023). Bis-phenoxides as Ligands for Ti-mediated Hydroamination and Pyrrole Formation Catalysis. Retrieved from the University Digital Conservancy, https://hdl.handle.net/11299/259692.
Content distributed via the University Digital Conservancy may be subject to additional license and use restrictions applied by the depositor. By using these files, users agree to the Terms of Use. Materials in the UDC may contain content that is disturbing and/or harmful. For more information, please see our statement on harmful content in digital repositories.