Readme created by Thomas R. Hoye ------------------- GENERAL INFORMATION ------------------- 1. Title of data set: Supporting data for "4-Carboalkoxylated Polyvalerolactones from Malic Acid: Tough and Degradable Polyesters" 2. Author Information: Principal Investigator Contact Information Name: Thomas R. Hoye Address: 207 Pleasant Street SE, Minneapolis, Minnesota 55455 Email: hoye@umn.edu Associate or Co-investigator Contact Information Name: Marc A. Hillmyer Address: 207 Pleasant Street SE, Minneapolis, Minnesota 55455 Email: hillmyer@umn.edu Associate or Co-investigator Contact Information Name: Grant W. Fahnhorst Address: 207 Pleasant Street SE, Minneapolis, Minnesota 55455 Email: fahn0018@umn.edu Associate or Co-investigator Contact Information Name: Guilhem X. De Hoe Address: 207 Pleasant Street SE, Minneapolis, Minnesota 55455 Email: dehoe001@umn.edu 3. Date of data collection (single data, range, approximate date): 2018-2019 4. Geographic location of data collection: All data were collected at the University of Minnesota, Minneapolis, MN. 5. Information about funding sources that supported the collection of the data: The research was conducted with financial support from: i) an NSF-funded Center for Chemical Innovation, the NSF Center for Sustainable Polymers (CHE-1901635) and ii) the University of Minnesota Doctoral Dissertation Fellowship program. Some NMR data were collected on instruments that were purchased through the NIH Shared Instrumentation Grant Program (S10OD011952). -------------------------- SHARING/ACCESS INFORMATION -------------------------- 1. Licenses/restrictions placed on the data: CC0 1.0 Universal 2. Links to publications that cite or use the data: Fahnhorst, G., De Hoe, G., Hillmyer, M., & Hoye, T. (2020). 4-Carboalkoxylated Polyvalerolactones from Malic Acid: Tough and Degradable Polyesters. Macromolecules. https://10.1021/acs.macromol.0c00212 3. Links to other publicly accessible locations of the data: 4. Links/relationships to ancillary data sets: 5. Was data derived from another source? No 6. Recommended citation for the data: Hoye, Thomas; De Hoe, Guilhem; Fahnhorst, Grant; Hillmyer, Marc. (2020). Supporting data for "4-Carboalkoxylated Polyvalerolactones from Malic Acid: Tough and Degradable Polyesters". Retrieved from the Data Repository for the University of Minnesota, https://doi.org/10.13020/z341-jg60. --------------------- DATA & FILE OVERVIEW --------------------- Purpose Statement: This Readme document describes the structure of the data files. General Notes: Each type of data is collected in a single master folder (e.g., NMR spectra, SEC chromatograms, etc.) are segregated into separate folders. Files Contained: • ChemDraw MS and SI: the ChemDraw files for all schemes in the manuscript and supporting information are included as both .cdx and .png files. • IR Spetra: infrared (IR) spectra are provided as the .pdf files created by the insrument. • NMR Spectra: nuclear magnetic resonance (NMR) spectroscopy data is included for each sample as an MNova file. • Polymer Characterization: DSC data: differential scanning calorimetry (DSC) data is included for the figures that report DSC data. The raw data are provided as .tri files and worked up data as .xlsx files. Matrix-assisted laser desorption ionization time of flight (MALDI-TOF) data. SEC data: size exclusion chromatography (SEC) data for all of the polymers reported in the SI. The raw data are provided as .csv files. Tensile testing data: Stress-strain measurement raw data are provided as .csv files. TGA data: Thermogravimetric analysis (TGA) data are included for the figures that include TGA data. The raw data are provided as well as the worked up .xlsx files. • Polymer hydrolytic degradation Are there multiple versions of the dataset? N -------------------------- METHODOLOGICAL INFORMATION -------------------------- IR Spectroscopy (IR): IR spectra were recorded on a Bruker Alpha Platinum FTIR instrument containing an ATR single-bounce diamond crystal. NMR Spectroscopy (NMR): NMR spectra were collected on a Bruker Avance III 500 spectrometer operating at 500 MHz. Proton chemical shifts were referenced to tetramethylsilane as an internal standard. Carbon chemical shifts were referenced to the CDCl3 solvent resonance. Differential Scanning Calorimetry (DSC): Differential scanning calorimetry was performed on a TA Instruments Q-1000. Experiments were performed with hermetically sealed aluminum pans. The Tg was estimated as the midpoint of the thermal transition in the curve of the second heating ramp at 10 °C/min, which was calculated using the Trios software. Thermogravimetric Analysis (TGA): Thermogravimetric analysis was performed on a TA Instruments Q500 Analyzer at 10 °C min-1 to 550 °C under a nitrogen atmosphere. Size exclusion chromatography (SEC): Mass-average molar mass, number-average molar mass, and molar mass dispersity was measured using two Agilent 1100 series liquid chromatography instrument. Experiments were performed with three Phenomenex Phenogel-5 columns aligned in series with THF as the mobile phase or three Varian PLgel Mixed C Columns with chloroform as the mobile phase. A Wyatt Technology DAWN DSP MALLS detector and a Wyatt optlab EX RI detector were used to collect the chromatograms for the THF experiments and an HP1047A refractive index detector for the chloroform experiments. The dn/dc values were estimated with an “in-line” method that uses the total area of the RI signal for samples of a known concentration and assumes 100% of the sample mass is recovered. People involved with sample collection, processing, analysis and/or submission: Grant Fahnhorst performed the synthesis and collected the NMR, IR, MALDI, SEC, DSC, and TGA data. Guilhem De Hoe collected the tensile test data. Thomas R. Hoye submitted the data. Folder PATH listing Volume serial number is EADC-777B C:. | listmyfiles.text | README Draft.txt | +---ChemDraw MS and SI | +---Manuscript ChemDraw .cdx and .png files | | Figure 1.cdx | | Figure 1.png | | Figure 10.cdx | | Figure 10.png | | Figure 11.cdx | | Figure 11.png | | Figure 2.cdx | | Figure 2.png | | Figure 3.cdx | | Figure 3.png | | Figure 4.cdx | | Figure 4.png | | Figure 5.cdx | | Figure 5.png | | Figure 6.cdx | | Figure 6.png | | Figure 7.cdx | | Figure 7.png | | Figure 8.cdx | | Figure 8.png | | Figure 9.cdx | | Figure 9.png | | | \---Supporting Information Chemdraw .cdx and .png files | Figure S4.cdx | Figure S4.png | Figure S1.cdx | Figure S1.png | Figure S10.cdx | Figure S10.png | Figure S11.cdx | Figure S11.png | Figure S12.cdx | Figure S12.png | Figure S13.cdx | Figure S13.png | Figure S14.cdx | Figure S14.png | Figure S15.cdx | Figure S15.png | Figure S16.cdx | Figure S16.png | Figure S17.cdx | Figure S17.png | Figure S18.cdx | Figure S18.png | Figure S19.cdx | Figure S19.png | Figure S2.cdx | Figure S2.png | Figure S20.cdx | Figure S20.png | Figure S21.cdx | Figure S21.png | Figure S22.cdx | Figure S22.png | Figure S23.cdx | Figure S23.png | Figure S24.cdx | Figure S24.png | Figure S25.cdx | Figure S25.png | Figure S3.cdx | Figure S3.png | Figure S5.cdx | Figure S5.png | Figure S6.cdx | Figure S6.png | Figure S7.cdx | Figure S7.png | Figure S8.cdx | Figure S8.png | Figure S9.cdx | Figure S9.png | +---IR Spectra | PC2EtHexVL.pdf | PCBnVL.pdf | PCC11VL.pdf | PCEtVL.pdf | PCiPrVL.pdf | PCnBuVL.pdf | PCtBuVL.pdf | +---NMR Spectra | +---Polymers | | +---PC2EtHexVL | | | +---gwf-3-p073-PC2EtHexVL-13C | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | cpdprg2 | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | spnam5 | | | | | spnam8 | | | | | stanprogram23518 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | \---gwf-5-p183-PC2EtHexVL-1H | | | \---10 | | | | acqu | | | | acqus | | | | audita.txt | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram6101 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | +---PCBnVL | | | \---gwf-5-193-PCBnVL-1H and 13C | | | +---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram30411 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | \---11 | | | | acqu | | | | acqus | | | | audita.txt | | | | cpdprg2 | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram30411 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | +---PCC11VL | | | +---gwf-4-p172-PCC11VL-13C | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | cpdprg2 | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | spnam5 | | | | | spnam8 | | | | | stanprogram23518 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | \---gwf-5-p180-PCC11VL-1H | | | \---10 | | | | acqu | | | | acqus | | | | audita.txt | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram5554 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | +---PCEtVL | | | +---gwf-4-p242-PCEtVL-HiMW-1H and 13C | | | | +---10 | | | | | | acqu | | | | | | acqus | | | | | | audita.txt | | | | | | fid | | | | | | format.temp | | | | | | fq1list | | | | | | precom.output | | | | | | prosol_History | | | | | | pulseprogram | | | | | | scon2 | | | | | | shimvalues | | | | | | specpar | | | | | | stanprogram10870 | | | | | | uxnmr.info | | | | | | uxnmr.par | | | | | | vtc_pid_settings | | | | | | | | | | | \---pdata | | | | | \---1 | | | | | outd | | | | | proc | | | | | procs | | | | | title | | | | | | | | | \---11 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | cpdprg2 | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram10870 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | \---gwf-5-p203-PCEtVL-LowMW-1H | | | \---10 | | | | acqu | | | | acqus | | | | audita.txt | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram23608 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | +---PCiPrVL | | | +---gwf-4-p155-AcPolyCiPrVL-1H and 13C | | | | +---10 | | | | | | acqu | | | | | | acqus | | | | | | audita.txt | | | | | | fid | | | | | | format.temp | | | | | | fq1list | | | | | | precom.output | | | | | | prosol_History | | | | | | pulseprogram | | | | | | scon2 | | | | | | shimvalues | | | | | | specpar | | | | | | stanprogram20898 | | | | | | uxnmr.info | | | | | | uxnmr.par | | | | | | vtc_pid_settings | | | | | | | | | | | \---pdata | | | | | \---1 | | | | | outd | | | | | proc | | | | | procs | | | | | title | | | | | | | | | \---11 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | cpdprg2 | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram20898 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---gwf-4-p236-PCiPrVL-highMW-1H | | | | +---1 | | | | | | acqu | | | | | | acqus | | | | | | audita.txt | | | | | | fid | | | | | | format.temp | | | | | | fq1list | | | | | | precom.output | | | | | | pulseprogram | | | | | | scon2 | | | | | | shimvalues | | | | | | specpar | | | | | | uxnmr.info | | | | | | uxnmr.par | | | | | | vtc_pid_settings | | | | | | | | | | | \---pdata | | | | | \---1 | | | | | 1i | | | | | 1r | | | | | auditp.txt | | | | | outd | | | | | proc | | | | | procs | | | | | thumb.png | | | | | title | | | | | | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram4273 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | \---gwf-5-p203-PCiPrVL-lowMW-1H | | | \---10 | | | | acqu | | | | acqus | | | | audita.txt | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram23608 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | +---PCMeVL | | | \---gwf-5-p200-PCMeVL-HighMW | | | \---10 | | | | acqu | | | | acqus | | | | audita.txt | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram23608 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | +---PCnBuVL | | | +---gwf-4-p158-PCnBuVL-HiMW-1H and 13C | | | | +---10 | | | | | | acqu | | | | | | acqus | | | | | | audita.txt | | | | | | fid | | | | | | format.temp | | | | | | fq1list | | | | | | precom.output | | | | | | prosol_History | | | | | | pulseprogram | | | | | | scon2 | | | | | | shimvalues | | | | | | specpar | | | | | | stanprogram20898 | | | | | | uxnmr.info | | | | | | uxnmr.par | | | | | | vtc_pid_settings | | | | | | | | | | | \---pdata | | | | | \---1 | | | | | outd | | | | | proc | | | | | procs | | | | | title | | | | | | | | | \---11 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | cpdprg2 | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram20898 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | \---gwf-5-p191-PCnBuVL-lowMW-1H | | | \---10 | | | | acqu | | | | acqus | | | | audita.txt | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram3918 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | \---PCtBuVL | | \---gwf-5-p191-PtBuVL 1H and 13C | | +---10 | | | | acqu | | | | acqus | | | | audita.txt | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram3918 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | \---11 | | | acqu | | | acqus | | | audita.txt | | | cpdprg2 | | | fid | | | format.temp | | | fq1list | | | precom.output | | | prosol_History | | | pulseprogram | | | scon2 | | | shimvalues | | | specpar | | | stanprogram3918 | | | uxnmr.info | | | uxnmr.par | | | vtc_pid_settings | | | | | \---pdata | | \---1 | | outd | | proc | | procs | | title | | | +---Small Molecules | | +---2-ethylhexylated compounds | | | \---gwf-5-p176-C2EtHexVL 1H and 13C | | | +---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram5554 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | \---11 | | | | acqu | | | | acqus | | | | audita.txt | | | | cpdprg2 | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram5554 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | +---Benzylated compounds | | | \---gwf-5-p169-CBnVL 1H and 13C | | | +---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram25594 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | \---11 | | | | acqu | | | | acqus | | | | audita.txt | | | | cpdprg2 | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram25594 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | +---Ethylated compounds | | | +---gwf-3-p120-2-Et 1H and 13C | | | | +---10 | | | | | | acqu | | | | | | acqus | | | | | | audita.txt | | | | | | fid | | | | | | format.temp | | | | | | fq1list | | | | | | precom.output | | | | | | prosol_History | | | | | | pulseprogram | | | | | | scon2 | | | | | | shimvalues | | | | | | specpar | | | | | | stanprogram21206 | | | | | | uxnmr.info | | | | | | uxnmr.par | | | | | | vtc_pid_settings | | | | | | | | | | | \---pdata | | | | | \---1 | | | | | outd | | | | | proc | | | | | procs | | | | | title | | | | | | | | | \---11 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | cpdprg2 | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram21206 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---gwf-4-p286-Compound S2 1H and 13C | | | | +---10 | | | | | | acqu | | | | | | acqus | | | | | | audita.txt | | | | | | fid | | | | | | format.temp | | | | | | fq1list | | | | | | precom.output | | | | | | prosol_History | | | | | | pulseprogram | | | | | | scon2 | | | | | | shimvalues | | | | | | specpar | | | | | | stanprogram20379 | | | | | | uxnmr.info | | | | | | uxnmr.par | | | | | | vtc_pid_settings | | | | | | | | | | | \---pdata | | | | | \---1 | | | | | outd | | | | | proc | | | | | procs | | | | | title | | | | | | | | | \---11 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | cpdprg2 | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram20379 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | \---gwf3-p128-CEtVL-1H and 13C | | | +---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram19718 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | \---11 | | | | acqu | | | | acqus | | | | audita.txt | | | | cpdprg2 | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram19718 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | +---gwf-5-p167-methylbromoglutaric acid_Compound 4 1H and 13C | | | +---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram32286 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | \---11 | | | | acqu | | | | acqus | | | | audita.txt | | | | cpdprg2 | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | spnam5 | | | | spnam8 | | | | stanprogram32286 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | +---isoPropylated compounds | | | +---gwf-3-p121-Cmpd 2-iPr 13C | | | | +---10 | | | | | | acqu | | | | | | acqus | | | | | | audita.txt | | | | | | fid | | | | | | format.temp | | | | | | fq1list | | | | | | precom.output | | | | | | prosol_History | | | | | | pulseprogram | | | | | | scon2 | | | | | | shimvalues | | | | | | specpar | | | | | | stanprogram21206 | | | | | | uxnmr.info | | | | | | uxnmr.par | | | | | | vtc_pid_settings | | | | | | | | | | | \---pdata | | | | | \---1 | | | | | outd | | | | | proc | | | | | procs | | | | | title | | | | | | | | | \---11 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | cpdprg2 | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram21206 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---gwf-3-p187-Cmpd 2-iPr 1H | | | | \---1 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | 1i | | | | 1r | | | | auditp.txt | | | | outd | | | | proc | | | | procs | | | | thumb.png | | | | title | | | | | | | +---gwf-4-p112-CiPrVL 1H and 13C | | | | +---10 | | | | | | acqu | | | | | | acqus | | | | | | audita.txt | | | | | | fid | | | | | | format.temp | | | | | | fq1list | | | | | | precom.output | | | | | | prosol_History | | | | | | pulseprogram | | | | | | scon2 | | | | | | shimvalues | | | | | | specpar | | | | | | stanprogram15422 | | | | | | uxnmr.info | | | | | | uxnmr.par | | | | | | vtc_pid_settings | | | | | | | | | | | \---pdata | | | | | \---1 | | | | | outd | | | | | proc | | | | | procs | | | | | title | | | | | | | | | \---11 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | cpdprg2 | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram15422 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | \---gwf-5-p178-Cmpd S2 1H and 13C | | | +---1 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | 1i | | | | 1r | | | | auditp.txt | | | | outd | | | | proc | | | | procs | | | | thumb.png | | | | title | | | | | | | +---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram23518 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | \---11 | | | | acqu | | | | acqus | | | | audita.txt | | | | cpdprg2 | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram23518 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | +---nButylated compounds | | | +---gwf-3-p08-Cmpd 2-nBu-1H and 13C | | | | +---10 | | | | | | acqu | | | | | | acqus | | | | | | audita.txt | | | | | | fid | | | | | | format.temp | | | | | | fq1list | | | | | | precom.output | | | | | | prosol_History | | | | | | pulseprogram | | | | | | scon2 | | | | | | shimvalues | | | | | | specpar | | | | | | stanprogram21206 | | | | | | uxnmr.info | | | | | | uxnmr.par | | | | | | vtc_pid_settings | | | | | | | | | | | \---pdata | | | | | \---1 | | | | | outd | | | | | proc | | | | | procs | | | | | title | | | | | | | | | \---11 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | cpdprg2 | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram21206 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---gwf-3-p142-Cmpd 2-nBu_1H | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram11714 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---gwf-3-p201-CnBuVL_1H and 13C | | | | +---10 | | | | | | acqu | | | | | | acqus | | | | | | audita.txt | | | | | | fid | | | | | | format.temp | | | | | | fq1list | | | | | | precom.output | | | | | | prosol_History | | | | | | pulseprogram | | | | | | scon2 | | | | | | shimvalues | | | | | | specpar | | | | | | stanprogram6006 | | | | | | uxnmr.info | | | | | | uxnmr.par | | | | | | vtc_pid_settings | | | | | | | | | | | \---pdata | | | | | \---1 | | | | | 1i | | | | | 1r | | | | | auditp.txt | | | | | intrng | | | | | outd | | | | | proc | | | | | procs | | | | | title | | | | | | | | | +---11 | | | | | | acqu | | | | | | acqu2 | | | | | | acqu2s | | | | | | acqus | | | | | | audita.txt | | | | | | EA | | | | | | format.temp | | | | | | fq1list | | | | | | gpnam1 | | | | | | gradient_calib | | | | | | precom.output | | | | | | prosol_History | | | | | | pulseprogram | | | | | | scon2 | | | | | | ser | | | | | | shimvalues | | | | | | specpar | | | | | | stanprogram6006 | | | | | | uxnmr.info | | | | | | uxnmr.par | | | | | | vtc_pid_settings | | | | | | | | | | | \---pdata | | | | | \---1 | | | | | curdat2 | | | | | outd | | | | | proc | | | | | proc2 | | | | | proc2s | | | | | procs | | | | | title | | | | | | | | | \---12 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | cpdprg2 | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram6006 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | \---gwf-4-p286-Cmpd S4_1H and 13C | | | +---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram20379 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---11 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | cpdprg2 | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram20379 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | \---20 | | | | acqu | | | | acqus | | | | audita.txt | | | | cpdprg2 | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram20379 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | +---t-butylated compounds | | | +---gwf-5-p020-Cmpd 2-tBu_1H and 13C | | | | +---10 | | | | | | acqu | | | | | | acqus | | | | | | audita.txt | | | | | | fid | | | | | | format.temp | | | | | | fq1list | | | | | | precom.output | | | | | | prosol_History | | | | | | pulseprogram | | | | | | scon2 | | | | | | shimvalues | | | | | | specpar | | | | | | stanprogram5032 | | | | | | uxnmr.info | | | | | | uxnmr.par | | | | | | vtc_pid_settings | | | | | | | | | | | \---pdata | | | | | \---1 | | | | | outd | | | | | proc | | | | | procs | | | | | title | | | | | | | | | \---20 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | cpdprg2 | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | spnam5 | | | | | spnam8 | | | | | stanprogram5032 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---gwf-5-p123-Cmpd S5 1H and 13C | | | | +---15 | | | | | | acqu | | | | | | acqus | | | | | | audita.txt | | | | | | fid | | | | | | format.temp | | | | | | fq1list | | | | | | precom.output | | | | | | prosol_History | | | | | | pulseprogram | | | | | | scon2 | | | | | | shimvalues | | | | | | specpar | | | | | | stanprogram32286 | | | | | | uxnmr.info | | | | | | uxnmr.par | | | | | | vtc_pid_settings | | | | | | | | | | | \---pdata | | | | | \---1 | | | | | outd | | | | | proc | | | | | procs | | | | | title | | | | | | | | | +---16 | | | | | | acqu | | | | | | acqus | | | | | | audita.txt | | | | | | cpdprg2 | | | | | | fid | | | | | | format.temp | | | | | | fq1list | | | | | | precom.output | | | | | | prosol_History | | | | | | pulseprogram | | | | | | scon2 | | | | | | shimvalues | | | | | | specpar | | | | | | spnam5 | | | | | | spnam8 | | | | | | stanprogram32286 | | | | | | uxnmr.info | | | | | | uxnmr.par | | | | | | vtc_pid_settings | | | | | | | | | | | \---pdata | | | | | \---1 | | | | | outd | | | | | proc | | | | | procs | | | | | title | | | | | | | | | \---17 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | cpdprg2 | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram32286 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | \---gwf-5-p123-CtBuVL | | | +---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram30068 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | \---11 | | | | acqu | | | | acqus | | | | audita.txt | | | | cpdprg2 | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram30068 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | \---Undecylated compounds | | \---gwf-5-p177-CC11VL 1H and 13C | | +---10 | | | | acqu | | | | acqus | | | | audita.txt | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram5554 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | \---11 | | | acqu | | | acqus | | | audita.txt | | | cpdprg2 | | | fid | | | format.temp | | | fq1list | | | precom.output | | | prosol_History | | | pulseprogram | | | scon2 | | | shimvalues | | | specpar | | | stanprogram5554 | | | uxnmr.info | | | uxnmr.par | | | vtc_pid_settings | | | | | \---pdata | | \---1 | | outd | | proc | | procs | | title | | | \---Worked Up MNOVA NMR Files | NMR Files WU-Ethyl.mnova | NMR Files WU-iPr.mnova | NMR Files WU-nBu.mnova | NMR Files WU-Other small molecules.mnova | NMR Files WU-PCRVLs.mnova | NMR Files WU-tBu.mnova | Worked Up Low MW PCRVLs.mnova | +---Polymer Characterization | +---DSC_RawData and WorkedUp Excel | | +---High Molar Mass Raw DSC Files | | | gwf-4-p155-Acetylated-PCiPrVL.tri | | | gwf-4-p158-PCnBuVL.tri | | | gwf-4-p172-PCC11VL.tri | | | gwf-4-p236-PCiPrVl.001 | | | | | +---Low Molar Mass DSC Raw Data Files | | | gwf-5-p123-PCEtVL.tri | | | gwf-5-p123-PCiPrVL.tri | | | gwf-5-p180-PCC11VL.tri | | | gwf-5-p183-PC2-EtHexVL.tri | | | gwf-5-p191-PCnBuVL.tri | | | gwf-5-p191-PCtBuVL.tri | | | gwf-5-p193-PCBnVL.tri | | | gwf-5-p194-PCEtVLl.tri | | | gwf-5-p194-PCiPrVL.tri | | | gwf-5-p232-PCtBuVL.tri | | | | | +---PCEtVL HEat and hold DSC Raw Data | | | gwf-5-p164-PCEtVL-heatandholddifferentT.tri | | | gwf-5-p164-PCEtVL-heatat25C-4h.tri | | | GWF-5-P210-PCEtVL_5days after melt press.tri | | | GWF-5-P210-PCEtVL_70h@RT (1).tri | | | GWF-5-P210-PCEtVL_70h@RT.tri | | | GWF-5-P210-PCEtVL_95h@RT-onlyto20C.tri | | | GWF-5-P210-PCEtVL_95h@RT.tri | | | gwf-5-p232-PCEtVL_DSC_1.5month_only to 20C.tri | | | | | +---PCiPrVL heat and holds DSC Raw Data | | | gwf-4-p254-PCiPrVL-heat&hold22C.tri | | | gwf-5-p164-PCiPrVl-heat4hat35C.tri | | | gwf-5-p164-PCiPrVL-heatandholddifferentT (1).tri | | | gwf-5-p164-PCiPrVL-heatat 35C.tri | | | GWF-5-P210-PCiPrVL_7days after melt press.tri | | | GWF-5-P210_PCiPrVL_23h@RT.tri | | | GWF-5-P210_PCiPrVL_46h@RT.tri | | | | | +---PCMeVL heat and holds DSC Raw Data | | | gwf-5-p152-heat and hold-RT.tri | | | gwf-5-p152-polyCMVL-heat&holds-longer(1).tri | | | gwf-5-p152-polyCMVL-heat&holds-longer-65C (1).tri | | | gwf-5-p152-polyCMVL-heat&holds-longer-65C.tri | | | gwf-5-p152-polyCMVL-heat&holds-longer.tri | | | gwf-5-p152-polyCMVL-heat&holds.tri | | | gwf-5-p164-CMVL-new-heat25-1h35C4h.tri | | | GWF-5-P200-23Hannealedat35C-coolto-60.tri | | | GWF-5-P200-23Hannealedat35C.tri | | | gwf-5-p200-CMVL-heatat 35C(1).tri | | | gwf-5-p200-CMVL-heatat 35C.tri | | | GWF-5-P200_23h@35C_23h@RT.tri | | | GWF-5-P200_23h@35C_46h@RT.tri | | | GWF-5-P210-PCMVL_9days after melt press.tri | | | GWF-5-P220-PCMVLrepressed_day6.tri | | | gwf-5-p232-PCMVLreannealed-Aged1Month.tri | | | gwf-5-p232-PCMVLreannealed-StrainIndCryst.tri | | | | | +---PCnBuVL heat and holds DSC Raw Data | | | gwf-4-p158-PnBuVL-heat&hold22C.tri | | | gwf-5-p164-CnBuVL-heatandholddifferentT.tri | | | gwf-5-p164-nBuVL-heat and hold at RT.tri | | | GWF-5-P210-PCnBuVL_30h@RT.tri | | | GWF-5-P210-PCnBuVL_3days after melt press.tri | | | gwf-5-p232-PCnBuVL-only to 20C.tri | | | | | \---Worked Up Excel DSC Files | | PCEtVL Heat and holds.xlsx | | PCiPrVL_VariedMolarMass_DSC_DATA.xlsx | | PolyCiPrVL Heat and holds.xlsx | | PolyCMVL Heat and holds-AllOneRun.xlsx | | PolyCnBuVL Heat and holds.xlsx | | Worked up DSC Data for Low MolarMass.xlsx | | | +---MALDI_Worked Up Excel File | | MALDI_.xlsx | | | +---SEC_RawData and WorkedUp Excel | | +---CSV Files Raw Data Files | | | | GWF-4-P158-POLYCNBVL.CSV | | | | GWF-4-P236-POLYCIPVL.CSV | | | | GWF-4-P242-POLYCEVL.CSV | | | | | | | +---50mer files | | | | gwf-5-p180-polyC11[20181206].csv | | | | gwf-5-p180-polyC11[20181206].txt | | | | gwf-5-p183-poly2-EtHex[20181206].csv | | | | gwf-5-p183-poly2-EtHex[20181206].txt | | | | gwf-5-p191-polynBuValerolactone[20181210].txt | | | | gwf-5-p191-polytBuValerolactone[20181210].txt | | | | gwf-5-p193-polyCBnVL[20181220].txt | | | | gwf-5-p194-PolyCEtVl[20181220].txt | | | | gwf-5-p194-polyCiPrVL[20181220].txt | | | | | | | \---CSV Files Monitoring CiPrVL polymerization over time | | | gwf-5-p120-01h.csv | | | gwf-5-p120-2.5h.csv | | | gwf-5-p120-24h.csv | | | gwf-5-p120-48h.csv | | | gwf-5-p120-4h.csv | | | gwf-5-p120-96h.csv | | | gwf-5-p120-9h.csv | | | | | \---Worked Up SEC Files | | Worked Up high Molar Mass SEC traces.xlsx | | Worked Up Low Molar Mass SEC traces.xlsx | | Worked Up SEC traces for CiPrVLPolymerizationovertime 5_p120.xlsx | | | +---Tensile Testing_RawDate and Workedup Excel | | | Tensile Testing WorkedUp Excel Data.xlsx | | | | | \---RawData csv files | | 5-p220-PolyCMVLrepressed.csv | | gwf-5-p213-PolyCiPrVL.csv | | PolyCEVL 50 mm permin.csv | | polyCMVL-5-p212.csv | | | \---TGA_RawData and Worked Up Excel | +---Raw Data Files for TGA High MW samples | | gwf-4-p155-Ac-CiPrVL.005 | | gwf-4-p159-PCnBuVL.007 | | gwf-4-p172-PCC11VL.003 | | gwf-4-p236-PCiPrVl.001 | | gwf-4-p242-PCEtVL.007 | | | +---Raw Data Files for TGA n equal 50mers | | gwf-5-p180-PCC11VL.002 | | gwf-5-p183-PC2etHexVL.003 | | gwf-5-p191-PCnBuVL.001 | | gwf-5-p191-PCtBuVL.001 | | gwf-5-p193-PCBnVL.001 | | gwf-5-p193-PCEtVL.002 | | gwf-5-p193-PCiPrVL.003 | | gwf-5-p203-PCEtVL_2.001 | | gwf-5-p203-PCiPrVL_2 | | gwf-5-p203-PCiPrVL_2.001 | | | \---WorkedUp TGA Excel Files | TGA-Carboalkoxys-50mers_LowMolarMasses.xlsx | TGA-Carboalkoxys_HighMolarMasses.xlsx | \---Polymer H2O Degradations Figure 10 and Figure S48 plots.pxp PCRVL Degradation Data Work Up for Figures 10 and S48.xlsx PCRVL Degradation Raw Data for Figures 10 and S48.xlsx