This file ReadMe was updated on 2024-03-03 by Caitlin Sample ------------------- GENERAL INFORMATION ------------------- Recommended citation for the data: Sample, Caitlin S.; Hoehn, Brenden D.; Hillmyer, Marc A. Supporting Data for Crosslinked Polyolefins Through Tandem ROMP/Hydrogenation. Retrieved from the Data Repository for the University of Minnesota, https://doi.org/10.13020/s2rv-1918. Title of Dataset: Supporting Data for Crosslinked Polyolefins Through Tandem ROMP/Hydrogenation Author Information: Principal Investigator Contact Information Name: Marc A. Hillmyer Institution: University of Minnesota Address: Chemistry, Minneapolis, Minnesota 55455 Email: hillmyer@umn.edu ORCID: 0000-0001-8255-3853 Associate or Co-investigator Contact information Name: Caitlin S. Sample Institution: Arizona State University Address: Biodesign Institute, Tempe, Arizona 85281 Email: caitlin.sample@asu.edu ORCID: 0000-0002-8622-0180 Associate or Co-investigator Contact Information Name: Brenden D. Hoehn Institution: University of Minnesota Address: Chemical Engineering and Materials Science, Minneapolis, Minnesota 55455 Email: hoehn073@umn.edu ORCID: 0000-0002-3879-8842 Date of data collection (single date, range, approximate date): 2022-06-01 to 2023-07-01 Geographic location of data collection (where was data collected?): University of Minnesota This work was supported by the National Science Foundation (Award No. DMR-2003454). NMR experiments were performed on instruments supported by the Office of the Vice President of Research, College of Science and Engineering, the Department of Chemistry at the University of Minnesota, and the Office of the Director, National Institutes of Health of the National Institutes of Health (Award No. S10OD011952). FTIR measurements were carried out in the Characterization Facility, University of Minnesota, which receives partial support from the NSF through the MRSEC (Award Number DMR-2011401) and the NNCI (Award Number ECCS-2025124) programs. -------------------------- SHARING/ACCESS INFORMATION -------------------------- 1. Licenses/restrictions placed on the data: CC0 1.0 Universal 2. Links to publications that cite or use the data: Sample, Caitlin S.; Hoehn, Brenden D.; Hillmyer, Marc A. Crosslinked Polyolefins Through Tandem ROMP/Hydrogenation. ACS Macro Letters 2024, VOLUME (ISSUE), PP. https://doi.org/DOI 3. Links to other publicly accessible locations of the data: N/A 4. Links/relationships to ancillary data sets: N/A 5. Was data derived from another source? No --------------------- DATA & FILE OVERVIEW --------------------- Purpose Statement: This document describes the raw datafiles used to generate the figures in the article "Crosslinked Polyolefins Through Tandem ROMP/Hydrogenation". General Notes: The files are organized by Figure, Table, and Scheme, with the type of analysis noted in the folder name and in the filenames. Scheme and structure files are present as Chemdraw files (.cdxml) and images (.png). Nuclear Magnetic Resonance (NMR) files (folders and .mnova) can be opened with MNOVA. Differential Scanning Calorimetry (DSC) files are present as raw data files to be opened with TA Trios (.tri) and exported temperature and heat flow data that can be opened in Excel (.csv). Fourier-Transform Infrared (FTIR) spectroscopy files are present as raw data files to be opened in Omnic (.SPA) and exported wavenumber (1st column) and transmission (2nd column) data that can be opened in Excel (.csv). Tensile testing files can be opened with Excel (.csv). Experiments are listed as 1, 2, 3, etc or 1_1, 1_2, 1_3, etc. Files with same names are duplicates(such as C90D10_Tensile.csv), for example in "Figure 4 - Tensile" we chose a representative sample for each condition, but in "Figure S10 - Tensile" we show all samples tested for each condition. Rheology files can be opened with Excel (.csv). Gel fraction files can be opened with Excel (.csv). Image files are in jpeg format (.jpg). Other abbreviations used in the filenames are: PCOE - polycyclooctene PE - polyethylene COE - cyclooctene DCPD - dicyclopentadiene PCy3 - tricyclohexylphosphine TEP - triethyl phosphite Py - pyridine C90D10 - network made from 90% cyclooctene (COE), 10% dicyclopentadiene (DCPD) H-C90D10 - hydrogenated network made from 90% COE, 10% DCPD C10D90 - network made from 10% COE, 90% DCPD H-C10D90 - hydrogenated network made from 10% COE, 90% DCPD Are there multiple versions of the dataset? N Description of methods used for collection, generation, and processing of data: Additional supporting information is located with the published manuscript. People involved with sample collection, processing, analysis and/or submission: Caitlin S. Sample and Brenden D. Hoehn collected all FTIR and tensile testing data. Caitlin S. Sample collected all NMR, DSC, rheology, and gel fraction data, as well as all ------------------- Data Tree ------------------- \---Sample et al - Polyolefin Networks - Data Files | +---Figure 1 - NMR DSC | | PCOE-Hydrogenation_Scheme.cdxml | | PCOE-Hydrogenation_Scheme.png | | PCOEvsPE_NMR.mnova | | PCOE_DSC.csv | | PCOE_DSC.tri | | PE_DSC.csv | | PE_DSC.tri | | | +---PCOE_NMR | | \---10 | | | acqu | | | acqus | | | audita.txt | | | fid | | | format.temp | | | fq1list | | | precom.output | | | prosol_History | | | pulseprogram | | | scon2 | | | shimvalues | | | specpar | | | stanprogram15146 | | | uxnmr.info | | | uxnmr.par | | | vtc_pid_settings | | | | | \---pdata | | \---1 | | outd | | proc | | procs | | title | | | \---PE_NMR | \---1 | | acqu | | acqus | | audita.txt | | fid | | format.ased | | format.temp | | fq1list | | precom.output | | pulseprogram | | scon2 | | shimvalues | | specpar | | uxnmr.info | | uxnmr.par | | vtc_pid_settings | | | \---pdata | \---1 | 1i | 1r | auditp.txt | outd | proc | procs | thumb.png | title | +---Figure 2 - FTIR | C10D90_FTIR.CSV | C10D90_FTIR.SPA | C90D10_FTIR.CSV | C90D10_FTIR.SPA | H-C10D90_FTIR.CSV | H-C10D90_FTIR.SPA | H-C90D10_FTIR.CSV | H-C90D10_FTIR.SPA | ROMP-Hydrogenation_Scheme.cdxml | ROMP-Hydrogenation_Scheme.png | +---Figure 3 - DSC | C10D90_DSC.csv | C10D90_DSC.tri | C90D10_DSC.csv | C90D10_DSC.tri | H-C10D90_DSC.csv | H-C10D90_DSC.tri | H-C90D10_DSC.csv | H-C90D10_DSC.tri | +---Figure 4 - Tensile | C10D90_Tensile.csv | C90D10_Tensile.csv | H-C10D90_Tensile.csv | H-C90D10_Tensile.csv | +---Figure 5 - FTIR Tensile | C10D90-15days-air_FTIR.CSV | C10D90-15days-air_FTIR.SPA | C10D90-15days-air_Tensile.csv | C10D90-1day-N2_FTIR.CSV | C10D90-1day-N2_FTIR.SPA | C10D90-3days-N2_Tensile.csv | C90D10-15days-air_FTIR.CSV | C90D10-15days-air_FTIR.SPA | C90D10-15days-air_Tensile.CSV | C90D10-1day-N2_FTIR.CSV | C90D10-1day-N2_FTIR.SPA | C90D10-3days-N2_Tensile.csv | H-C10D90-14days-air_Tensile.csv | H-C10D90-15days-air_FTIR.CSV | H-C10D90-15days-air_FTIR.SPA | H-C10D90-1day-N2_FTIR.CSV | H-C10D90-1day-N2_FTIR.SPA | H-C10D90-3days-N2_Tensile.csv | H-C90D10-15days-air_FTIR.CSV | H-C90D10-15days-air_FTIR.SPA | H-C90D10-15days-air_Tensile.csv | H-C90D10-1day-N2_FTIR.CSV | H-C90D10-1day-N2_FTIR.SPA | H-C90D10-3days-N2_Tensile.csv | +---Figure S1 - Rheology | 10equivPCy3_Rheology.xls | 1equivPCy3_Rheology.xls | 20equivPCy3_Rheology.xls | 2equivPCy3_Rheology.xls | 40equivPCy3_Rheology.xls | 4equivPCy3_Rheology.xls | +---Figure S10 - Tensile | C10D90_Tensile.csv | C90D10_Tensile.csv | H-C10D90_Tensile.csv | H-C90D10_Tensile.csv | +---Figure S11 - DSC | H-C90D10-PostTensile_DSC.csv | H-C90D10-PostTensile_DSC.tri | H-C90D10-PreTensile_DSC.csv | H-C90D10-PreTensile_DSC.tri | +---Figure S12 - Images | C10D90-15days-air_Image.jpg | C90D10-15days-air_Image.jpg | H-C10D90-14days-air_Image.jpg | H-C90D10-15days-air_Image.jpg | +---Figure S13 - Tensile | C10D90-15days-air_Tensile.csv | C10D90-15days-N2_Tensile.csv | C10D90-3days-N2_Tensile.csv | C90D10-15days-air_Tensile.csv | C90D10-15days-N2_Tensile.csv | C90D10-3days-N2_Tensile.csv | H-C10D90-14days-air_Tensile.csv | H-C10D90-14days-N2_Tensile.csv | H-C10D90-3days-N2_Tensile.csv | H-C90D10-15days-air_Tensile.csv | H-C90D10-15days-N2_Tensile.csv | H-C90D10-3days-N2_Tensile.csv | +---Figure S2 - NMR | | PCy3_NMR.mnova | | | \---PCy3_NMR | \---10 | | acqu | | acqus | | audita.txt | | fid | | format.temp | | fq1list | | precom.output | | prosol_History | | pulseprogram | | scon2 | | shimvalues | | specpar | | stanprogram15873 | | uxnmr.info | | uxnmr.par | | vtc_pid_settings | | | \---pdata | \---1 | outd | proc | procs | title | +---Figure S3 - NMR | | PCOE-Hydrogenation-Inhibitors_NMR.mnova | | PCOE-Hydrogenation-Inhibitors_Scheme.cdxml | | PCOE-Hydrogenation-Inhibitors_Scheme.png | | | +---PCOE-Hydrogenation-NoInhibitor_NMR | | \---1 | | | acqu | | | acqus | | | audita.txt | | | fid | | | format.ased | | | format.temp | | | fq1list | | | precom.output | | | pulseprogram | | | scon2 | | | shimvalues | | | specpar | | | uxnmr.info | | | uxnmr.par | | | vtc_pid_settings | | | | | \---pdata | | \---1 | | 1i | | 1r | | auditp.txt | | outd | | proc | | procs | | thumb.png | | title | | | +---PCOE-Hydrogenation-PCy3_NMR | | \---1 | | | acqu | | | acqus | | | audita.txt | | | fid | | | format.ased | | | format.temp | | | fq1list | | | precom.output | | | pulseprogram | | | scon2 | | | shimvalues | | | specpar | | | uxnmr.info | | | uxnmr.par | | | vtc_pid_settings | | | | | \---pdata | | \---1 | | 1i | | 1r | | auditp.txt | | outd | | proc | | procs | | thumb.png | | title | | | +---PCOE-Hydrogenation-Py_NMR | | \---1 | | | acqu | | | acqus | | | audita.txt | | | fid | | | format.ased | | | format.temp | | | fq1list | | | precom.output | | | pulseprogram | | | scon2 | | | shimvalues | | | specpar | | | uxnmr.info | | | uxnmr.par | | | vtc_pid_settings | | | | | \---pdata | | \---1 | | 1i | | 1r | | auditp.txt | | outd | | proc | | procs | | thumb.png | | title | | | \---PCOE-Hydrogenation-TEP_NMR | \---1 | | acqu | | acqus | | audita.txt | | fid | | format.ased | | format.temp | | fq1list | | precom.output | | pulseprogram | | scon2 | | shimvalues | | specpar | | uxnmr.info | | uxnmr.par | | vtc_pid_settings | | | \---pdata | \---1 | 1i | 1r | auditp.txt | outd | proc | procs | thumb.png | title | +---Figure S4 - NMR | | Hydrogenation-VariableT_NMR.mnova | | Hydrogenation-VariableT_Scheme.cdxml | | Hydrogenation-VariableT_Scheme.png | | | +---Hydrogenation-100degC_NMR | | \---1 | | | acqu | | | acqus | | | audita.txt | | | fid | | | format.ased | | | format.temp | | | fq1list | | | precom.output | | | pulseprogram | | | scon2 | | | shimvalues | | | specpar | | | uxnmr.info | | | uxnmr.par | | | vtc_pid_settings | | | | | \---pdata | | \---1 | | 1i | | 1r | | auditp.txt | | outd | | proc | | procs | | thumb.png | | title | | | +---Hydrogenation-120degC_NMR | | \---1 | | | acqu | | | acqus | | | audita.txt | | | fid | | | format.ased | | | format.temp | | | fq1list | | | precom.output | | | pulseprogram | | | scon2 | | | shimvalues | | | specpar | | | uxnmr.info | | | uxnmr.par | | | vtc_pid_settings | | | | | \---pdata | | \---1 | | 1i | | 1r | | auditp.txt | | outd | | proc | | procs | | thumb.png | | title | | | +---Hydrogenation-40degC_NMR | | \---1 | | | acqu | | | acqus | | | audita.txt | | | fid | | | format.ased | | | format.temp | | | fq1list | | | precom.output | | | pulseprogram | | | scon2 | | | shimvalues | | | specpar | | | uxnmr.info | | | uxnmr.par | | | vtc_pid_settings | | | | | \---pdata | | \---1 | | 1i | | 1r | | auditp.txt | | outd | | proc | | procs | | thumb.png | | title | | | +---Hydrogenation-60degC_NMR | | \---1 | | | acqu | | | acqus | | | audita.txt | | | fid | | | format.ased | | | format.temp | | | fq1list | | | precom.output | | | pulseprogram | | | scon2 | | | shimvalues | | | specpar | | | uxnmr.info | | | uxnmr.par | | | vtc_pid_settings | | | | | \---pdata | | \---1 | | 1i | | 1r | | auditp.txt | | outd | | proc | | procs | | thumb.png | | title | | | \---Hydrogenation-80degC_NMR | \---1 | | acqu | | acqus | | audita.txt | | fid | | format.ased | | format.temp | | fq1list | | precom.output | | pulseprogram | | scon2 | | shimvalues | | specpar | | uxnmr.info | | uxnmr.par | | vtc_pid_settings | | | \---pdata | \---1 | 1i | 1r | auditp.txt | outd | proc | procs | thumb.png | title | +---Figure S5 - DSC | Hydrogenation-120degC_DSC.csv | Hydrogenation-120degC_DSC.tri | Hydrogenation-40degC_DSC.csv | Hydrogenation-40degC_DSC.tri | Hydrogenation-60degC_DSC.csv | Hydrogenation-60degC_DSC.tri | Hydrogenation-80degC_DSC.csv | Hydrogenation-80degC_DSC.tri | PCOE_DSC.csv | PCOE_DSC.tri | +---Figure S6 - Gel fraction | LowDCPD_GelFraction.xlsx | +---Figure S7 - FTIR | Hydrogenation-120degC-minus200um_FTIR.CSV | Hydrogenation-120degC-minus200um_FTIR.SPA | Hydrogenation-120degC-surface_FTIR.CSV | Hydrogenation-120degC-surface_FTIR.SPA | Hydrogenation-140degC-center_FTIR.CSV | Hydrogenation-140degC-center_FTIR.SPA | Hydrogenation-140degC-surface_FTIR.SPA | Hydrogenation-140degC-surface_FTIR.SPA.CSV | +---Figure S8 - DSC FTIR | C10D90-air_DSC.csv | C10D90-air_DSC.tri | C10D90-N2_DSC.csv | C10D90-N2_DSC.tri | C10D90-postDSC_FTIR.CSV | C10D90-postDSC_FTIR.SPA | C10D90-preDSC_FTIR.CSV | C10D90-preDSC_FTIR.SPA | +---Figure S9 - Images | C10D90-PostTensile_Image.jpg | C10D90-PreTensile_Image.jpg | C90D10-PostTensile_Image.jpg | C90D10-PreTensile_Image.jpg | H-C10D90-PostTensile_Image.jpg | H-C10D90-PreTensile_Image.jpg | H-C90D10-PostTensile_Image.jpg | H-C90D10-PreTensile_Image.jpg | +---Scheme 1 | CrosslinkedPolyolefins_Scheme.cdxml | CrosslinkedPolyolefins_Scheme.png | \---Table S1 - Tensile C10D90-15days-air_Tensile.csv C10D90-15days-N2_Tensile.csv C10D90-3days-N2_Tensile.csv C90D10-15days-air_Tensile.csv C90D10-15days-N2_Tensile.csv C90D10-3days-N2_Tensile.csv H-C10D90-14days-air_Tensile.csv H-C10D90-14days-N2_Tensile.csv H-C10D90-3days-N2_Tensile.csv H-C90D10-15days-air_Tensile.csv H-C90D10-15days-N2_Tensile.csv H-C90D10-3days-N2_Tensile.csv