This readme.txt file was generated on 2023-04-06 by Sidhu, Nathan; Mastalski, Isaac; Dauenhauer, Paul. (2023). Data for On the Intrinsic Reaction Kinetics of Polypropylene Pyrolysis. Retrieved from the Data Repository for the University of Minnesota, https://doi.org/10.13020/y009-3y91. ------------------- GENERAL INFORMATION ------------------- 1. Title of Dataset: Data for On the Intrinsic Reaction Kinetics of Polypropylene Pyrolysis 2. Author Information Author Contact: Paul J. Dauenhauer (hauer@umn.edu) Name: Nathan Sidhu Institution: University of Minnesota - Twin Cities Email: sidhu016@umn.edu ORCID: 0000-0003-4186-6874 Name: Isaac Mastalski Institution: University of Minnesota - Twin Cities Email: masta062@umn.edu ORCID: 0000-0002-9039-3455 Name: Paul Dauenhauer Institution: University of Minnesota - Twin Cities Email: hauer@umn.edu ORCID: 0000-0001-5810-1953 3. Date published or finalized for release: 2023-04-05 4. Date of data collection: 2018-08-01 to 2018-08-31 5. Geographic location of data collection: University of Minnesota - Twin Cities, Amundson Hall, 421 Washington Ave SE, Minneapolis, MN 55455 6. Information about funding sources that supported the collection of the data: ExxonMobil Technology and Engineering Company, University of Minnesota Center for Sustainable Polymers (grant number CHE-1901635) 7. Overview of the data: The data here contain high-speed videos (1000 fps) of polypropylene thin films pyrolyzed at 500–700 °C for 2.0 seconds. These videos are in support of the publication entitled “On the Intrinsic Reaction Kinetics of Polypropylene Pyrolysis.” The original videos were recorded at 1000 fps using a Phantom eX-2 high-speed camera with a macro lens (Carl Zeiss Makro-Planar 2/100 zf.2) attached with Nikon PK-13, PK-12, PK-13, and PK-11A extension rings. The reactor system was illuminated with a high-power directional light source (Prior, Lumen 2000). The original videos have been cut to only include the 2.0 seconds of footage capturing the reaction pulses of the visual experiments. -------------------------- SHARING/ACCESS INFORMATION -------------------------- 1. Licenses/restrictions placed on the data: Attribution-NonCommercial-NoDerivs 3.0 United States (http://creativecommons.org/licenses/by-nc-nd/3.0/us/) 2. Links to publications that cite or use the data: Sidhu, N., Mastalski, I., Zolghadr, A., Patel, B., Uppili, S., Go, T., . . . Dauenhauer, P. (2023). On the Intrinsic Reaction Kinetics of Polypropylene Pyrolysis. ChemRxiv. https://doi.org/10.26434/chemrxiv-2023-kqqx1 3. Was data derived from another source? No If yes, list source(s): 4. Terms of Use: Data Repository for the U of Minnesota (DRUM) By using these files, users agree to the Terms of Use. https://conservancy.umn.edu/pages/drum/policies/#terms-of-use --------------------- DATA & FILE OVERVIEW --------------------- File List Filename: Video_S01_500_C_Side_View_30_fps.mp4 Short description: Video_S01: This video shows a 15 µm film of PP being reacted at 500 °C for 2.0 s in the Visual PHASR system (side view). This video is published at a framerate of 30 fps (~33.3 times slower than real-time). Filename: Video_S02_500_C_Side_View_1000_fps.mp4 Short description: Video_S02: This video shows a 15 µm film of PP being reacted at 500 °C for 2.0 s in the Visual PHASR system (side view). This video is published at a framerate of 1000 fps (real-time) and is the same footage as Video_S01. Filename: Video_S03_550_C_Side_View_30_fps.mp4 Short description: Video_S03: This video shows a 15 µm film of PP being reacted at 550 °C for 2.0 s in the Visual PHASR system (side view). This video is published at a framerate of 30 fps (~33.3 times slower than real-time). Filename: Video_S04_550_C_Side_View_1000_fps.mp4 Short description: Video_S04: This video shows a 15 µm film of PP being reacted at 550 °C for 2.0 s in the Visual PHASR system (side view). This video is published at a framerate of 1000 fps (real-time) and is the same footage as Video_S03. Filename: Video_S05_600_C_Side_View_30_fps.mp4 Short description: Video_S05: This video shows a 15 µm film of PP being reacted at 600 °C for 2.0 s in the Visual PHASR system (side view). This video is published at a framerate of 30 fps (~33.3 times slower than real-time). Filename: Video_S06_600_C_Side_View_1000_fps.mp4 Short description: Video_S06: This video shows a 15 µm film of PP being reacted at 600 °C for 2.0 s in the Visual PHASR system (side view). This video is published at a framerate of 1000 fps (real-time) and is the same footage as Video_S05. Filename: Video_S07_650_C_Side_View_30_fps.mp4 Short description: Video_S07: This video shows a 15 µm film of PP being reacted at 650 °C for 2.0 s in the Visual PHASR system (side view). This video is published at a framerate of 30 fps (~33.3 times slower than real-time). Filename: Video_S08_650_C_Side_View_1000_fps.mp4 Short description: Video_S08: This video shows a 15 µm film of PP being reacted at 650 °C for 2.0 s in the Visual PHASR system (side view). This video is published at a framerate of 1000 fps (real-time) and is the same footage as Video_S07. Filename: Video_S09_700_C_Side_View_30_fps.mp4 Short description: Video_S09: This video shows a 15 µm film of PP being reacted at 700 °C for 2.0 s in the Visual PHASR system (side view). This video is published at a framerate of 30 fps (~33.3 times slower than real-time). Filename: Video_S10_700_C_Side_View_1000_fps.mp4 Short description: Video_S10: This video shows a 15 µm film of PP being reacted at 700 °C for 2.0 s in the Visual PHASR system (side view). This video is published at a framerate of 1000 fps (real-time) and is the same footage as Video_S09. Filename: Video_S11_500_C_Top_View_30_fps.mp4 Short description: Video_S11: This video shows a 15 µm film of PP being reacted at 500 °C for 2.0 s in the Visual PHASR system (top view). This video is published at a framerate of 30 fps (~33.3 times slower than real-time). Filename: Video_S12_500_C_Top_View_1000_fps.mp4 Short description: Video_S12: This video shows a 15 µm film of PP being reacted at 500 °C for 2.0 s in the Visual PHASR system (top view). This video is published at a framerate of 1000 fps (real-time) and is the same footage as Video_S11. Filename: Video_S13_550_C_Top_View_30_fps.mp4 Short description: Video_S13: This video shows a 15 µm film of PP being reacted at 550 °C for 2.0 s in the Visual PHASR system (top view). This video is published at a framerate of 30 fps (~33.3 times slower than real-time). Filename: Video_S14_550_C_Top_View_1000_fps.mp4 Short description: Video_S14: This video shows a 15 µm film of PP being reacted at 550 °C for 2.0 s in the Visual PHASR system (top view). This video is published at a framerate of 1000 fps (real-time) and is the same footage as Video_S13. Filename: Video_S15_600_C_Top_View_30_fps.mp4 Short description: Video_S15: This video shows a 15 µm film of PP being reacted at 600 °C for 2.0 s in the Visual PHASR system (top view). This video is published at a framerate of 30 fps (~33.3 times slower than real-time). Filename: Video_S16_600_C_Top_View_1000_fps.mp4 Short description: Video_S16: This video shows a 15 µm film of PP being reacted at 600 °C for 2.0 s in the Visual PHASR system (top view). This video is published at a framerate of 1000 fps (real-time) and is the same footage as Video_S15. Filename: Video_S17_650_C_Top_View_30_fps.mp4 Short description: Video_S17: This video shows a 15 µm film of PP being reacted at 650 °C for 2.0 s in the Visual PHASR system (top view). This video is published at a framerate of 30 fps (~33.3 times slower than real-time). Filename: Video_S18_650_C_Top_View_1000_fps.mp4 Short description: Video_S18: This video shows a 15 µm film of PP being reacted at 650 °C for 2.0 s in the Visual PHASR system (top view). This video is published at a framerate of 1000 fps (real-time) and is the same footage as Video_S17. Filename: Video_S19_700_C_Top_View_30_fps.mp4 Short description: Video_S19: This video shows a 15 µm film of PP being reacted at 700 °C for 2.0 s in the Visual PHASR system (top view). This video is published at a framerate of 30 fps (~33.3 times slower than real-time). Filename: Video_S20_700_C_Top_View_1000_fps.mp4 Short description: Video_S20: This video shows a 15 µm film of PP being reacted at 700 °C for 2.0 s in the Visual PHASR system (top view). This video is published at a framerate of 1000 fps (real-time) and is the same footage as Video_S19. -------------------------- METHODOLOGICAL INFORMATION -------------------------- 1. Description of methods used for collection/generation of data: The original videos were recorded at 1000 fps using a Phantom eX-2 high-speed camera with a macro lens (Carl Zeiss Makro-Planar 2/100 zf.2) attached with Nikon PK-13, PK-12, PK-13, and PK-11A extension rings. The reactor system was illuminated with a high-power directional light source (Prior, Lumen 2000). 2. Methods for processing the data: The original videos have been cut to only include the 2.0 seconds of footage capturing the reaction pulses of the visual experiments. No other processing was performed. 3. Instrument- or software-specific information needed to interpret the data: N/A 4. Standards and calibration information, if appropriate: N/A 5. Environmental/experimental conditions: The polypropylene thin films were pyrolyzed at 500–700 °C for 2.0 seconds under a He atmosphere. The full details of the experiment are provided in the manuscript "On the Intrinsic Reaction Kinetics of Polypropylene Pyrolysis." 6. People involved with sample collection, processing, analysis and/or submission: Sidhu, Nathan; Mastalski, Isaac; Zolghadr, Ali; Dauenhauer, Paul J.