This file ReadMe was updated on 2022-11-13 by Jay Werber Suggested Citation: Werber, Jay R; Hillmyer, Marc A; Peterson, Colin H; Stipanic, Dean F. (2022). Supporting Data for Polymeric Microcapsules as Robust Mimics of Emulsion Liquid Membranes for Selective Ion Separations. Retrieved from the Data Repository for the University of Minnesota, https://doi.org/10.13020/8wyz-xv68. ------------------- GENERAL INFORMATION ------------------- Title of Dataset: Supporting data for Polymeric Microcapsules as Robust Mimics of Emulsion Liquid Membranes for Selective Ion Separations Author Information: Principal Investigator Contact Information Name: Marc A. Hillmyer Institution: University of Minnesota Address: Chemistry, Minneapolis, Minnesota 55455 Email: hillmyer@umn.edu Associate or Co-investigator Contact information Name: Jay R. Werber Institution: University of Toronto Address: 200 College St, Rm 214, Toronto, ON, M5S3E5, Canada Email: jay.werber@utoronto.ca Associate or Co-investigator Contact Information Name: Colin Peterson Institution: University of Minnesota Address: Chemistry, Minneapolis, Minnesota 55455 Email: pet00842@umn.edu Associate or Co-investigator Contact Information Name: Dean F. Stipanic Institution: University of Toronto Address: 200 College St, Rm 214, Toronto, ON, M5S3E5, Canada Email: dean.stipanic@mail.utoronto.ca Date of data collection: 2019-01-01 to 2022-09-30 Geographic location of data collection (where was data collected?): University of Minnesota, University of Toronto Information about funding sources that supported the collection of the data: This research was supported by a grant from the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number DE-SC-0020210 and a grant from the Natural Sciences and Engineering Research Council of Canada under Award Number RGPIN-2021-02729. -------------------------- SHARING/ACCESS INFORMATION -------------------------- 1. Licenses/restrictions placed on the data: CC0 1.0 Universal 2. Links to publications that cite or use the data: https://doi.org/10.1021/acs.est.2c07242 3. Links to other publicly accessible locations of the data: N/A 4. Links/relationships to ancillary data sets: N/A 5. Was data derived from another source? No --------------------- DATA & FILE OVERVIEW --------------------- Purpose Statement: This document describes the raw datafiles used to generate the figures in the article "Polymeric Microcapsules as Robust Mimics of Emulsion Liquid Membranes for Selective Ion Separations". General Notes: The files are organized by Figure, with the type of analysis noted in the folder name and in the filenames. UV-Vis data is exported into Excel files and organized by wavelength (nm) and absorbance. NMR files can be opened with MNOVA. SEC files are present as exported dRI data in Excel and as raw data files to be opened with Astra. IR files are exported into Excel files and organized by wavenumber (cm^-1) and transmittance. SEM files are tiff image files, and are the original files generated during electron microscopy. Optical micrographs are tiff image files, and are the original files generated during microscopy. Ruler images are also included for calibration. DSC files are present as XLS exports and .TRI files to be opened with TA Trios software. ICP-OES files are present as XLS exports, containing raw data and processed data. SAXS files are present as txt files of the one-dimensional azimuthally averaged data. The columns are q (A^-1), relative intensity (cm-1), and the statistical error in intensity associated with the averaging method (cm^-1). Are there multiple versions of the dataset? N -------------------------- METHODOLOGICAL INFORMATION -------------------------- Description of methods used for collection, generation, and processing of data: Ultraviolet-visible (UV-Vis) spectroscopy was conducted on a Shimadzu spectrophotometer. Polyethyleneimine was used for the colorimetric determination of Cu(II). Dimethylglyoxime was used for the colorimetric determination of Ni(II). Nuclear magnetic resonance (NMR) spectroscopy was conducted on a Bruker Advance III HD 500 spectrometer. Chemical shifts are reported in δ units, expressed in ppm downfield of tetramethylsilane, using a residual CHCl3 peak as an internal standard (CDCl3, 1H: 7.26 ppm). Size exclusion chromatography (SEC) was conducted in THF at 25 °C, 1 mL/min, on an Agilent Infinity 1260 HPLC system equipped with three Waters Styragel HR columns in series, a Wyatt DAWN HELEOS-II 18-angle laser light scattering detector, and a Wyatt Optilab T-rEX differential refractive index detector. Polystyrene standards with conventional calibration were used to estimate molar mass. Differential scanning calorimetry (DSC) was conducted on a TA Instruments Discovery DSC using aluminum T-zero pans with hermetic lids. Infrared (IR or ATR-FTIR)) spectroscopy was conducted on a Bruker Alpha Platinum ATR spectrometer with a diamond ATR crystal. Optical microscopy was conducted using an AmScope digital microscope. Emulsions were placed between a coverslip and slide. Microcapsules were imaged on a slide without a coverslip. Small angle x-ray scattering (SAXS) was conducted on a Xenocs Ganesha LabSAXS instrument. The sample detector distance was 826 mm and the exposure time was 240 s. Azimuthal averaging was performed using DataSqueeze software (https://www.physics.upenn.edu/~heiney/datasqueeze/index.html). Scanning electron microscopy (SEM) was conducted on a Hitachi SU8230 instrument. Prior to SEM, samples were coated with 3 nm of Pt using a Leica ACE600 coater. Inductively coupled plasma-optical emission spectroscopy (ICP-OES) was conducted by the UMN Research Analytical Laboratory for the reuse study on an iCap 7600 Duo. For four of the six column experiments, an Agilent 720 series instrument was used. Raw data is included in the Agilent data in Fig 6 folder. People involved with sample collection, processing, analysis and/or submission: Jay Werber - Sample preparation, UV-Vis, NMR, SEC, IR, optical microscopy, SEM Colin Peterson - DSC, SAXS Dean Stipanic - Sample preparation, ICP-OES -------------------------- DATA TREE -------------------------- \---DRUM - EST - Microcapsules | BeadPrepMasses_ExtractionEstimation.xlsx | +---Fig 1 - SAXS | JAY-chp-05-088.docx | latest_0015729_caz_plot.txt | latest_0015730_caz_plot.txt | latest_0015731_caz_plot.txt | latest_0015732_caz_plot.txt | latest_0015733_caz_plot.txt | SAXS analysis.xlsx | +---Fig 2 - Micrographs | +---Optical Micrograph | | +---Calibration | | | 10x ruler.tif | | | 40x ruler.tif | | | 4x ruler 1 mm total.tif | | | | | +---Microcapsules - JRW-3-125 | | \---W-O-W Emulsion - JRW-3-127 | | 3-127 wow 10x 1.tif | | 3-127 wow 10x 2.tif | | 3-127 wow 10x 3.tif | | 3-127 wow 10x 4.tif | | 3-127 wow 10x 5.tif | | 3-127 wow 40x 1.tif | | 3-127 wow 40x 2.tif | | 3-127 wow 40x 3.tif | | 3-127 wow 40x 4.tif | | 3-127 wow 40x 5.tif | | 3-127 wow 40x 6.tif | | 3-127 wow 40x 7.tif | | 3-127 wow 4x 1.tif | | 3-127 wow 4x 2.tif | | 3-127 wow 4x 3.tif | | 3-127 wow 4x 4.tif | | | \---SEM | \---JRW-3-125 | JRW-3-_0013.tif | JRW-3-_0013.txt | JRW-3-_0014.tif | JRW-3-_0014.txt | JRW-3-_0015.tif | JRW-3-_0015.txt | JRW-3-_0016.tif | JRW-3-_0016.txt | JRW-3-_0017.tif | JRW-3-_0017.txt | JRW-3-_0018.tif | JRW-3-_0018.txt | JRW-3-_0019.tif | JRW-3-_0019.txt | +---Fig 3-5 - Batch Uptake | | BatchExperiments_Data_CleanForDRUM.xlsx | | | \---Batch Uptake UV-Vis Raw Data | JRW-3-127 UV-Vis.xlsx | JRW-3-129 UV-Vis Cu uptake.xlsx | JRW-3-130 UV-VIs Cu uptake.xlsx | JRW-3-131 UV-VIs.xlsx | JRW-3-132 UV-VIs.xlsx | JRW-3-133 UV-VIs.xlsx | JRW-3-135 UV-Vis Cu and Ni uptake.xlsx | JRW-3-139 UV-Vis Cu and Ni uptake.xlsx | JRW-3-142 UV-Vis Cu uptake batch.xlsx | JRW-3-143_144_145_146 Cu.xlsx | +---Fig 6 - Column Uptake | | ColumnRuns.xlsx | | | +---ICP-OES | | 0.1mM CuSO4.xlsx | | 1mM CuSO4.xlsx | | | \---UV-Vis | JRW-3-127 UV-Vis.xlsx | JRW-3-141 UV-Vis.xlsx | +---Fig 7 - Column Reuse | Column_Reuse_Concentration.xlsx | JRW-3-141 UV-Vis.xlsx | X027 20-21 Analytical Data Report ICP-OES data.xlsx | +---Fig S1 - SBS NMR - SEC | | SBS NMR.mnova | | | \---SEC | SBS D1157[020221] ---jrw-3-136.csv | SBS D1157[020221].afe7 | +---Fig S10 - ATR-FTIR - PI-PSSA1 | JRW-3-064 81 86 PI-PSSA1.xlsx | +---Fig S11 - ATR-FTIR - PI-PSSA2 | JRW-3-109_114 PI-PSSE PI-PSSA.xlsx | +---Fig S12 - S15 - S16 - Micrographs - See Fig 2 Folder | See Fig 2 folder for micrographs.txt | +---Fig S2 - DSC | JRW-3-140_SBS_Lix.tri | JRW-3-140_SBS_Lix.xls | JRW-3-147_SBS_particles.tri | JRW-3-147_SBS_particles.xls | +---Fig S20 - Extraction Cu Ni with SBS Film | JRW-3-140 Extraction SBS.xlsx | +---Fig S21-S23 - Ni UV-Vis | Fig S21 UV-Vis.xlsx | Fig S22 UV-Vis.xlsx | Fig S23 UV-Vis.xlsx | +---Fig S3 - UV-Vis Calibration | Fig S3 - UV-Vis.xlsx | +---Fig S4 - Lix 84-I NMR | JRW-02-063 HNAPO purification.mnova | Lix 84-I.mnova | +---Fig S5 - Solvent Extraction | JRW-3-151 SX with Buffered Cu.xlsx | +---Fig S6 - Polyisoprene NMR | JRW-03-064 PI.mnova | +---Fig S7 - PI-PSSE1 NMR | JRW-3-081 PI-PSSE1 NMR.mnova | +---Fig S8 - PI-PSSE2 NMR | JRW-3-109 PI-PSSE2 NMR.mnova | +---Fig S9 - PI-PSSE SEC | JRW-3-064 PI[10232020].afe7 | JRW-3-064 PI[10232020].csv | JRW-3-081 PI-PSSE[112520].afe7 | JRW-3-081 PI-PSSE[112520].csv | JRW-3-109 PI-PSSE[020221].afe7 | JRW-3-109 PI-PSSE[020221].csv | \---Modeling | 2022-04-21 Kp calc.xlsx | \---Model Outputs Cu_model_0pt0percLix.xlsx Cu_model_0pt1percLix.xlsx Cu_model_0pt5percLix.xlsx Cu_model_1percLix_100mMH2SO4.xlsx Cu_model_1percLix_20mMH2SO4.xlsx Cu_model_1percLix_500mMH2SO4.xlsx