This README file was created by Marianne Meyersohn Suggested Citation: Meyersohn, Marianne S; Haque, Farihah M; Hillmyer, Marc A. (2023). Supporting data for Dynamic Aliphatic Polyester Elastomers Crosslinked with Aliphatic Dianhydrides. Retrieved from the Data Repository for the University of Minnesota, https://doi.org/10.13020/qewn-zh14. ------------------- GENERAL INFORMATION ------------------- Title of Dataset: Supporting Data for Dynamic Aliphatic Polyester Elastomers Crosslinked with Aliphatic Dianhydrides. Author Information: Principal Investigator Contact Information Name: Marc A. Hillmyer Institution: University of Minnesota Address: DEPARTMENT OF CHEMISTRY, 207 Pleasant Street SE, Minneapolis, Minnesota 55455 Email: hillmyer@umn.edu Associate or Co-investigator Contact information Name: Marianne Meyersohn Institution: University of Minnesota Address: DEPARTMENT OF CHEMISTRY, 207 Pleasant Street SE, Minneapolis, Minnesota 55455 Email: meye3190@umn.edu Associate or Co-investigator Contact Information Name: Farihah M. Haque Institution: University of Minnesota Address: DEPARTMENT OF CHEMISTRY, 207 Pleasant Street SE, Minneapolis, Minnesota 55455 Email: haque050@umn.edu Date of data collection (September 2020 – February 2022) Geographic location of data collection: University of Minnesota Information about funding sources that supported the collection of the data: This research was supported by a grant from the National Science Foundation through the Center for Sustainable Polymers (grant CHE-1901635). -------------------------- SHARING/ACCESS INFORMATION -------------------------- 1. Licenses/restrictions placed on the data: CC0 1.0 Universal 2. Links to publications that cite or use the data: https://doi.org/10.1021/acspolymersau.3c00004 3. Links to other publicly accessible locations of the data: 4. Links/relationships to ancillary data sets: 5. Was data derived from another source? --------------------- DATA & FILE OVERVIEW --------------------- Purpose Statement: This document describes raw data and associated interpreted data used in the manuscript "Dynamic Aliphatic Polyester Elastomers Crosslinked with Aliphatic Dianhydrides." General Notes: The primary data are zipped and organized into 8 distinct folders, the title of each contains the type of data contained. ChemDraw: the ChemDraw files for all schemes in the manuscript and supporting information are included as .cdx and .jpg's. Raw 1H NMR data is organized into 6 distinct subfolders each containing raw NMR data for each type of experiment. The kinetics data is titled based on “experiment type_temperature_timepoint” (in minutes). For example “Transest_Kinetics_120C_60min” corresponds to transesterification kinetics done at 120 °C, timepoint of 60 minutes. Raw data under each subfolder is organized by the nomenclature established in the manuscript based on crosslinker type. Ex: CHDA and CBDA Raw Stress Relaxation data is based on crosslinker type, temperature of experiment and initial strain of experiment. Ex: “CBDA-100deg-5perstr” describes a film that was prepared using the CBDA crosslinker, a stress relaxation experiment run at 100 °C at 5% strain. Stress Relaxation data from supporting information figures are listed as “SI_X_CHDA-xdeg-5perstr.” Raw IR data nomenclature is based on the crosslinker type, temperature and time crosslinked at that temperature. Ex: “CBDA-film-24h-120C-1h-180C” describes a film that was prepared using the CBDA crosslinker and crosslinked at 120 °C for 24h followed by 180 °C for 1h. Raw DMTA data is organized by crosslinker type. Raw Shear Rheology data is organized by crosslinker type and experiment type. strswp means strain sweep; tempswpcycle means temperature sweep. Raw SEC data includes only RI detector and normalized intensities. All raw nuclear magnetic resonance spectroscopy data files can be accessed using MNova or Bruker software. CDX files can be viewed with ChemDraw, which is a proprietary software distributed by CambridgeSoft. All other files can be opened using Microsoft Excel. 1H-NMR stands for proton nuclear magnetic resonance spectroscopy. SEC stands for size exclusion chromatography, IR stands for infrared spectroscopy, DMTA stands for dynamic mechanical thermal analysis. -------------------------- METHODOLOGICAL INFORMATION -------------------------- General: Chloroform, hexane, and methanol were obtained from Fisher Scientific and used without any further purification. All other reagents and solvents were obtained from Sigma-Aldrich unless otherwise noted. ?-Methyl-?-caprolactone was purchased from Renewable Solutions LLC and was distilled prior to usage. Trimethylol propane was recrystallized from ethyl acetate (2x) and dried under vacuum (24 h) before storing in the glovebox. Diphenyl phosphate was dried under vacuum for 48 hours and stored in the glovebox under inert atmosphere. NMR Spectroscopy: 1H and 13C nuclear magnetic resonance (NMR) spectra were obtained on a 500 MHz Bruker Advance III spectrometer. Molar masses of polymers were obtained by end-group analysis. Fourier transform infrared spectra (FTIR): Data was obtained on a Bruker Alpha Platinum spectrometer equipped with a diamond crystal in attenuated total reflection (ATR) mode. A resolution of 4 cm-1 and 32 scans were done for each sample. Thermogravimetric analysis: was performed on a TA Instruments Q500 Analyzer. Samples were heated from room temperature to 500 °C at a rate of 10 °C min-1 under nitrogen atmosphere. A typical sample size was 5–10 mg. Differential scanning calorimetry (DSC) measurements were performed on a TA Instruments Discovery Series differential scanning calorimeter. Samples were analyzed in hermetically sealed T-Zero aluminum pans (2–6 mg). Samples were heated to 200 °C at 10 °C min-1 for the first cycle and subsequently cooled to –80 °C at 10 °C min-1 followed by a second heat cycle to 200 °C. Gel Fractions: Extractions of sol fractions were performed using tetrahydrofuran (THF). Approximately 30 mg of crosslinked elastomer was immersed in a tared vial with 20 mL of THF for 24 hours before the solvent was decanted. The swollen sample was then dried in a vacuum oven at 45 °C for 24 hours before the final mass was measured. The gel fraction was calculated by dividing the mass of the dried sample by the mass of the initial sample prior to swelling. Dynamic mechanical thermal analysis: Dynamic mechanical thermal analysis (DMTA) and stress relaxation experiments were conducted on an TA-instruments RSA-G2 analyzer with rectangular shaped samples in a tensile geometry. Samples were cut from films directly with a thickness of approximately 0.5 mm, a gauge length of 7 mm and gauge width of 3 mm. Experiments were conducted under nitrogen atmosphere. For DMTA experiments, samples were cooled to –80 °C with liquid nitrogen and the axial force was adjusted to 0.0 N to ensure no buckling. Once at –80 °C, the axial force was set to 0.10 N of tension. Samples were heated at a rate of 5 °C min-1 to 200 °C with an oscillatory strain of 0.05% and an angular frequency of 6.28 rad s-1 (1 Hz). Stress relaxation experiments were conducted under nitrogen atmosphere. Samples were placed within the grips and the axial force was adjusted to 0.10 N of tension. Samples were equilibrated at the desired temperature for 10 minutes. A 5% step strain was applied, and the modulus was monitored for 10 4 s. The modulus of each sample was normalized so comparison could be done across temperatures. Shear rheology was performed on a TA Instruments ARES Classic using 8 mm parallel plates under nitrogen atmosphere. Prior to each temperature sweep experiment, a strain sweep was performed from 0.1 to 10% with a frequency of 6.28 rad s-1 and a linear response was observed. The crosslinked sample was then equilibrated at 100 °C for 10 minutes. Following this the sample was heated to 180 °C at a rate of 5 °C min-1 and then cooled back to 100 °C for a total of 3 cycles. Tensile Data: A Shimadzu Autograph AGS-X series instrument was used to conduct uniaxial extension and hysteresis tests on the crosslinked polyester elastomers at room temperature. Samples were placed in flat grips and sandpaper was used to prevent slipping. Samples were extended at a rate of 50 mm min -1 until material failure. The extension experiments were performed with 5 replicates per sample. The Young’s modulus was calculated using the Trapezium software from 0-10% strain. For hysteresis experiments, one dogbone of each sample was subjected to cyclical loading (50% strain) and unloading for 20 cycles. The hysteresis energy loss was calculated by subtracting the hysteresis unloading curve from the loading curve. Method for collecting timepoints. Aliquots were taken at desired timepoints and rapidly cooled to room temperature and diluted in deuterated chloroform for 1H NMR analysis. Synthesis of mono-1-dodecyl cyclohexyl carboxylic acid To a 20 mL vial, 1,2, cyclohexane carboxylic anhydride (414 mg, 5.36 mmol) and dodecanol (500 mg, 5.36 mmol) was added and mixed with a teflon coated stir bar to homogenize the mixture. The reaction was placed in an oil bath at 120 °C and was reacted for 1 hr. Upon completion, there was no presence of anhydride and minimal dodecanol (<1%) left by 1H NMR spectroscopy. This compound was used without further purification. Synthesis of cyclohexyl dodecyl ester To a 100 mL flask dodecanol (1.5 g, 8 mmol) was added and dissolved in 50 mL of dry dichloromethane. Pyridine (0.8 mL, 9.60 mmol) was added to the flask. The vessel was then purged with nitrogen gas and cooled to 0 °C in an ice bath. Once cooled, cyclohexyl carbonyl chloride (1.3 mL, 9.60 mmol) was added dropwise to the flask. The reaction was left stirring at room temperature for 16 h. The reaction was cooled again to 0 °C in an ice bath and 25 mL of water was added to kill off any excess cyclohexyl carbonyl chloride. The contents were transferred to a separatory funnel where the organic layer was separated from the aqueous layer. The following washes were performed: 2x 1M NaOH, 2x 1M HCl and 1x brine. The solution was stirred over magnesium sulfate, filtered and the solvent was removed under reduced pressure. Synthesis of star shaped hydroxyl terminated poly(?-methyl-?-caprolactone) (PMCL) In a typical polymerization, a 75 mL pressure vessel was loaded with ?-methyl-?-caprolactone (20.0 g, 156 mmol), trimethylol propane (TMP) (268 mg, 2 mmol) and diphenyl phosphate (DPP) (395 mg, 1.56 mmol) under nitrogen atmosphere. A Teflon stir bar was added to aid TMP and DPP dissolution in MCL. The vessel was sealed and removed from inert atmosphere and placed in a 120 °C oil bath for 2 hours. At this point, the reaction mixture had become viscous and was no longer stirring. The reaction was cooled with an ice bath and then opened. Triethylamine (0.28 mL, 2 mmol) was added to the pressure vessel to quench DPP. Chloroform was added to double the volume in the pressure vessel and the crude PMCL was dissolved over 2 hours. PMCL was then precipitated twice into cold methanol and once into hexanes and transferred to a tared jar. The pure polymer was dried under a stream of nitrogen gas overnight before it was placed in a vacuum oven and dried for 24 hours at room temperature. The temperature was then elevated to 60 °C where the polymer was dried for 48 hours. Preparation of crosslinked polyester elastomers with dianhydrides. To prepare the crosslinked polyester elastomers, three arm star shaped PMCL (2.0 g) Mn = 10 kg/ mol was dissolved in THF (2mL) in a 20 mL vial with a Teflon coated stir bar. To a separate vial, 1,2,4,5, cyclohexane tetracarboxylic dianhydride (CHDA) (67 mg, 0.3 mmol) or 1,2,3,4, cyclobutane tetracarboxylic dianhydride (CBDA) (58 mg, 0.3 mmol) was dissolved in 0.5 mL of DMF. The PMCL endgroup to anhydride ratio was 1:1. The two solutions were mixed to form a homogenous solution and then casted onto a Teflon dish (6 cm diameter). A small amount of THF (1 mL) was used to finish the transfer and the solvent cast mixtures were then placed under a stream of nitrogen for 24 hours. After drying the solvent, the pans were placed in a preheated oven at 120 °C (or 180 °C) under nitrogen atmosphere and left to react for 24 hours. People involved with sample collection, processing, analysis and/or submission: Marianne Meyersohn- sample collection, processing, analysis Farihah Haque- sample collection Marc A Hillmyer- submission --------------------- DATA TREE --------------------- C:. | listmyfiles.text | +---Chemdraws | Esterification Model Reaction.cdxml | Esterification Model Reaction.jpg | Formation of Anhydride at Crosslink Junction from Carboxylic Acid.cdxml | Formation of Anhydride at Crosslink Junction from Carboxylic Acid.jpg | General Synthesis Polymer to Elastomeer Scheme.cdxml | General Synthesis Polymer to Elastomeer Scheme.jpg | IR Scheme Transesterification.cdxml | IR Scheme Transesterification.jpg | Reference Transesterification Reaction.cdxml | Reference Transesterification Reaction.jpg | Transesterification Model Reaction.cdxml | Transesterification Model Reaction.jpg | +---Raw_DMTA | CBDA-DMTA-80to200.xls | CHDA-DMTA-80to200.xls | +---Raw_IR | CBDA-film-24h-120C-1h-180C.dpt | CBDA-film-24h-120C-2h-180C.dpt | CBDA-film-24h-120C.dpt | CBDA-film-2h-120C.dpt | CBDA-film-preheat.dpt | CBDA_crosslinker.dpt | CHDA-film-1h-120C.dpt | CHDA-film-24h-120C-1h-180C.dpt | CHDA-film-24h-120C-2h-180C.dpt | CHDA-film-24h-120C.dpt | CHDA-film-5.5h-120C.dpt | CHDA-film-preheat.dpt | CHMA_model_anhydride.dpt | P4MCL-3armstar.dpt | +---Raw_NMR | +---Raw_Dodecyl_monoester | | \---10 | | | acqu | | | acqus | | | audita.txt | | | fid | | | format.temp | | | prosol_History | | | pulseprogram | | | scon2 | | | shimvalues | | | specpar | | | uxnmr.info | | | uxnmr.par | | | vtc_pid_settings | | | | | \---pdata | | \---1 | | outd | | proc | | procs | | title | | | +---Raw_NMR_Kinetics | | +---Raw_Esterification_NMR_Kinetics | | | +---Est_Kinetics_100C_12mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_100C_16mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_100C_1mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_100C_2mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_100C_4mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_100C_6mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_100C_8mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_120C_1mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_120C_2mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_120C_4mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_120C_6mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_120C_8mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_40C_16mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_40C_1mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram16802 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_40C_24mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_40C_2mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_40C_32mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_40C_48mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues 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| | | | | | | +---Est_Kinetics_40C_79mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_40C_8mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_60C_16mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_60C_1mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_60C_24mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_60C_2mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_60C_32mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_60C_48mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_60C_4mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_60C_60mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_60C_8mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_80C_16mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_80C_1mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_80C_24mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_80C_2mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Est_Kinetics_80C_4mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | \---Est_Kinetics_80C_8mn | | | \---10 | | | | acqu | | | | acqus | | | | audita.txt | | | | fid | | | | format.temp | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | +---Raw_Transesterification_Mechanism_NMR_Kinetics | | | +---Transesterification-150C-1to1-10min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-1to1-15min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-1to1-20min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-1to1-2min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-1to1-30min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-1to1-5min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-1to1-i | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-1to2-10min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-1to2-15min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-1to2-20min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-1to2-2min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-1to2-30min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-1to2-5min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-2to1-10min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-2to1-15min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-2to1-20min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-2to1-2min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-2to1-30min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-2to1-5min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-2to1-i | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-5to1_excess_ester-0min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram3657 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-5to1_excess_ester-10min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram3657 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-5to1_excess_ester-15min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram3657 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-5to1_excess_ester-2min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram3657 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-5to1_excess_ester-30min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram3657 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-5to1_excess_ester-45min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram3657 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transesterification-150C-5to1_excess_ester-5min | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram3657 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | \---Transesterification-150C-5to1_excess_ester-60min | | | \---10 | | | | acqu | | | | acqus | | | | audita.txt | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram3657 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | +---Raw_Transesterification_NMR_Kinetics | | | +---Transest_Kinetics_120C-10mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_120C-120mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_120C-15mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_120C-1mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram30115 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_120C-30mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_120C-45mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_120C-5mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_120C-60mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_120C-90mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_130C-10mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_130C-120mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_130C-1mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_130C-30mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_130C-45mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_130C-5mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_130C-60mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_130C-90mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_140C_10mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_140C_120mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_140C_1mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | fq1list | | | | | precom.output | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | stanprogram30115 | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_140C_30mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_140C_45mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_140C_5mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_140C_60mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_140C_90mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_150C_10mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_150C_120mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_150C_1mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_150C_30mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_150C_45mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_150C_5mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_150C_60mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_150C_90mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_160C_10mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_160C_120mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_160C_1mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_160C_30mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_160C_45mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_160C_5mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | +---Transest_Kinetics_160C_60mn | | | | \---10 | | | | | acqu | | | | | acqus | | | | | audita.txt | | | | | fid | | | | | format.temp | | | | | prosol_History | | | | | pulseprogram | | | | | scon2 | | | | | shimvalues | | | | | specpar | | | | | uxnmr.info | | | | | uxnmr.par | | | | | vtc_pid_settings | | | | | | | | | \---pdata | | | | \---1 | | | | outd | | | | proc | | | | procs | | | | title | | | | | | | \---Transest_Kinetics_160C_90mn | | | \---10 | | | | acqu | | | | acqus | | | | audita.txt | | | | fid | | | | format.temp | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | \---Raw_Transesterification_Reference_Kinetics | | +---Reference_Transesterification-150C-0min | | | \---10 | | | | acqu | | | | acqus | | | | audita.txt | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram20093 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | +---Reference_Transesterification-150C-10min | | | \---10 | | | | acqu | | | | acqus | | | | audita.txt | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram20093 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | +---Reference_Transesterification-150C-120min | | | \---10 | | | | acqu | | | | acqus | | | | audita.txt | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram20093 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | +---Reference_Transesterification-150C-20min | | | \---10 | | | | acqu | | | | acqus | | | | audita.txt | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram20093 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | +---Reference_Transesterification-150C-30min | | | \---10 | | | | acqu | | | | acqus | | | | audita.txt | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram20093 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | +---Reference_Transesterification-150C-45min | | | \---10 | | | | acqu | | | | acqus | | | | audita.txt | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram20093 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | +---Reference_Transesterification-150C-5min | | | \---10 | | | | acqu | | | | acqus | | | | audita.txt | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram20093 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | +---Reference_Transesterification-150C-60min | | | \---10 | | | | acqu | | | | acqus | | | | audita.txt | | | | fid | | | | format.temp | | | | fq1list | | | | precom.output | | | | prosol_History | | | | pulseprogram | | | | scon2 | | | | shimvalues | | | | specpar | | | | stanprogram20093 | | | | uxnmr.info | | | | uxnmr.par | | | | vtc_pid_settings | | | | | | | \---pdata | | | \---1 | | | outd | | | proc | | | procs | | | title | | | | | \---Reference_Transesterification-150C-90min | | \---10 | | | acqu | | | acqus | | | audita.txt | | | fid | | | format.temp | | | fq1list | | | precom.output | | | prosol_History | | | pulseprogram | | | scon2 | | | shimvalues | | | specpar | | | stanprogram20093 | | | uxnmr.info | | | uxnmr.par | | | vtc_pid_settings | | | | | \---pdata | | \---1 | | outd | | proc | | procs | | title | | | \---Raw_PMCL | +---13C_P4MCL | | | acqu | | | acqus | | | audita.txt | | | cpdprg2 | | | fid | | | format.temp | | | fq1list | | | precom.output | | | prosol_History | | | pulseprogram | | | scon2 | | | shimvalues | | | specpar | | | stanprogram15079 | | | uxnmr.info | | | uxnmr.par | | | vtc_pid_settings | | | | | \---pdata | | \---1 | | outd | | proc | | procs | | title | | | \---1H_P4MCL | | acqu | | acqus | | audita.txt | | fid | | format.temp | | fq1list | | precom.output | | prosol_History | | pulseprogram | | scon2 | | shimvalues | | specpar | | stanprogram26602 | | uxnmr.info | | uxnmr.par | | vtc_pid_settings | | | \---pdata | \---1 | outd | proc | procs | title | +---Raw_Rheology_Shear | CBDA-elastomer-strain_sweep.txt | CBDA-elastomer-tempswpcycle.txt | CHDA-elastomer-strain_sweep.txt | CHDA-elastomer-tempswpcycle.txt | +---Raw_SEC | SEC_PMCL_flowing_elastomer_networks_S17.xlsx | +---Raw_Stress_Relaxation | CBDA-100deg-5perstr.xls | CBDA-120deg-5perstr.xls | CBDA-140deg-5perstr.xls | CBDA-160deg-5perstr.xls | CBDA-180deg-5perstr.xls | CHDA-120deg-5perstr.xls | CHDA-140deg-5perstr.xls | CHDA-160deg-5perstr.xls | CHDA-180deg-5perstr.xls | S14_CBDA-100deg-5perstr.xlsx | S14_CBDA-140deg-5perstr.xlsx | S14_CBDA-160deg-5perstr.xlsx | S14_CBDA-180deg-5perstr.xlsx | S15_CBDA_24h180Cxlink_140deg_5perstr.xlsx | S15_CBDA_3h180Cxlink_140deg_5perstr.xls | +---Raw_Tensile | CBDA_hysteresis.xlsx | CHDA_CBDA_Tensile_Data.xlsx | CHDA_hysteresis.xlsx | Tensile_testing_commercial_RB.xlsx | \---Raw_TGA TGA_isothermal_180C.xlsx TGA_P4MCL_dianhydride_films.xlsx